64420-97-9

Basic information

• Product Name: 2-NITROBIPHENYL-2',3',4',5',6'-D5
• Synonyms: 2-NITROBIPHENYL-2',3',4',5',6'-D5;2-Phenylnitrobenzene-d5;NSC 5532-d5;o-Nitrodiphenyl-d5
• CAS NO: 64420-97-9
• Molecular Formula: C₁₂H₉NO₂
• Molecular Weight: 204.24
• Product Categories: Isotope Labeled Compounds;Mutagenesis Research Chemicals;Isotope Labelled Compounds
• Mol File: 64420-97-9.mol
• Article Data: 5

Chemical Properties

• Appearance: /
• Storage Temp.: -20°C Freezer
• Solubility: Chloroform (Slightly), Ethyl Acetate (Slightly)
• CAS DataBase Reference: 2-NITROBIPHENYL-2',3',4',5',6'-D5(CAS DataBase Reference)
• NIST Chemistry Reference: 2-NITROBIPHENYL-2',3',4',5',6'-D5(64420-97-9)
• EPA Substance Registry System: 2-NITROBIPHENYL-2',3',4',5',6'-D5(64420-97-9)

Safety Data

• Hazardous Substances Data: 64420-97-9(Hazardous Substances Data)

Usage

Chemical Properties

Pale Yellow Oil

Uses

2-Nitrobiphenyl-2’,3’,4’,5’,6’-d5 (cas# 64420-97-9) is a compound useful in organic synthesis.

Upstream product

• 1076-43-3 benzene-d6 
• 88-74-4 2-nitro-aniline 
• 609-73-4 o-nitroiodobenzene 
• 577-19-5 2-nitrophenyl bromide 
• 215527-70-1 2,3,4,5,6-pentadeuteriumbenzeneboronic acid 
• 4165-57-5 bromobenzene-d5 

Relevant articles and documents

LIGHT-EMITTING DEVICE AND ELECTRONIC APPARATUS INCLUDING THE LIGHT-EMITTING DEVICE

The disclosure relates to a light-emitting device including a first electrode, a second electrode facing the first electrode, and an interlayer disposed between the first electrode and the second electrode and including an emission layer. The interlayer includes a first compound represented by Formula 1 of the specification, a second compound represented by Formula 2 of the specification, and a third compound, which is a blue phosphorescent compound. The disclosure also relates to an electronic apparatus including the light-emitting device.

HETEROCYCLIC COMPOUND, LIGHT-EMITTING DEVICE INCLUDING HETEROCYCLIC COMPOUND, AND ELECTRONIC APPARATUS INCLUDING LIGHT-EMITTING DEVICE

A heterocyclic compound represented by Formula 1: wherein, in Formula 1, Ar1 to Ar4, Ar4, Ar11, and Ar12 are each, independently from one another, as defined herein.

Radical Annulations and Cyclisations with Isonitriles: the Fate of the Intermediate Imidoyl and Cyclohexadienyl Radicals

The reaction of 4-methoxyphenylisonitrile with phenylacetylene and AIBN produces a novel cyclopenta-fused quinoxalin through addition of 2-cyanoprop-2-yl radical to the alkyne; the resultinge vinyl radical attacks isonitrile to afford an imidoyl radical, which gives rise to a tandem 5-exo, 6-endo cyclisation.The whole process entails a new example of a rare 4 + 1 radical annulation.The cyanopropyl radical can also attack isonitrile to yield small amounts of quinolines deriving from 4 + 2 and 3 + 2 annulation between the resulting imidoyl radicals and phenylacetylene.The oxidation step leading to the final aromatic products involves the starting isonitrile, which is converted to an α-unsubstituted imidoyl radical and affords 2-unsubstituted quinolines.This behaviour was also found in cyclisations of biphenyl-2-ylisonitrile under various radical conditions.Finally, the title reaction gives small ammounts of an α,β-unsaturated nitrile, which can arise from a spirocyclohexadienyl radical through fragmentation and subsequent β-scission of the resulting iminyl.This could be the first, direct evidence of the intermediacy of iminyl radicals in the rearrangements of the spirocyclohexadienyls obtained by 3 + 2 annulation between imidoyl radicals and alkynes.