64424-57-3

Upstream product

• 82665-47-2 [(OC)2Fe(P(CH₃)2C₆H₅)2SCSCH(C₆H₅)CH₂COC₆H₅]⁽¹⁺⁾*PF₆^(1-)=[(OC)2Fe(P(CH₃)2C₆H₅)2SCSCH(C₆H₅)CH₂COC₆H₅]PF₆ 
• 15321-51-4 diiron nonacarbonyl 
• 672-66-2 Dimethyl(phenyl)phosphine 

Downstream Products

• 76648-78-7 Fe(η2-CS2CH2Ph)(Br)(CO)(PMe2Ph)2 
• 76648-75-4 (Fe(η2-CS2CH2Ph)(CO)2(PMe2Ph)2)PF6 
• 82665-47-2 [(OC)2Fe(P(CH₃)2C₆H₅)2SCSCH(C₆H₅)CH₂COC₆H₅]⁽¹⁺⁾*PF₆^(1-)=[(OC)2Fe(P(CH₃)2C₆H₅)2SCSCH(C₆H₅)CH₂COC₆H₅]PF₆ 
• 82665-45-0 [(OC)2Fe(P(CH₃)2C₆H₅)2SCSCH₂CH₂COCH₃]⁽¹⁺⁾*PF₆^(1-)=[(OC)2Fe(P(CH₃)2C₆H₅)2SCSCH₂CH₂COCH₃]PF₆ 
• 86176-29-6 [(CO)2(PMe₂Ph)2Fe(SCS)Pt(Cl)(PPh₃)2]BF₄ 
• 82665-49-4 [(OC)2Fe(P(CH₃)2C₆H₅)2SCSCH₂CH₂COOCH₃]⁽¹⁺⁾*PF₆^(1-)=[(OC)2Fe(P(CH₃)2C₆H₅)2SCSCH₂CH₂COOCH₃]PF₆ 
• 82665-43-8 [(OC)2Fe(P(CH₃)2C₆H₅)2SCSCH₂CH₂CHO]⁽¹⁺⁾*PF₆^(1-)=[(OC)2Fe(P(CH₃)2C₆H₅)2SCSCH₂CH₂CHO]PF₆ 

Relevant academic research and scientific papers

Regio- and stereoselective addition of (carbon disulfide)iron complexes to α,β-unsaturated carbonyls in the presence of strong acids

The Fe(η2-CS2)(CO)2(PR3)2 complexes add to α,β-unsaturated aldehydes, ketones, and esters in the presence of HPF6 or HBF4 to afford carbonyl derivatives having a bulky, cationic organometallic group at C-3. Cyclic substrates such as l-carvone and β-angelicalactone showed the stereoselectivity of the addition.