64448-06-2

Basic information

• Product Name: Phosphonium, triphenyl-, (phenylimino)ethenylide
• CAS NO: 64448-06-2
• Molecular Formula: C26H20NP
• Molecular Weight: 377.425
• Mol File: 64448-06-2.mol

Chemical Properties

• CAS DataBase Reference: Phosphonium, triphenyl-, (phenylimino)ethenylide(CAS DataBase Reference)
• NIST Chemistry Reference: Phosphonium, triphenyl-, (phenylimino)ethenylide(64448-06-2)
• EPA Substance Registry System: Phosphonium, triphenyl-, (phenylimino)ethenylide(64448-06-2)

Safety Data

• Hazardous Substances Data: 64448-06-2(Hazardous Substances Data)

Upstream product

• 622-44-6 phenylcarbonimidic dichloride 
• 19493-09-5 Methylenetriphenylphosphorane 

Downstream Products

• 64723-83-7 N-Phenyl-2-(triphenylphosphoranyliden)acetimidsaeure-methylester 
• 73818-38-9 4-Methyl-N-[1-phenylamino-2-(triphenyl-λ⁵-phosphanylidene)-eth-(Z)-ylidene]-benzenesulfonamide 
• 90963-70-5 [4-Furan-2-yl-6-phenyl-3-(triphenyl-λ⁵-phosphanylidene)-3,4-dihydro-pyran-(2Z)-ylidene]-phenyl-amine 
• 97004-49-4 1-Ethoxy-N-phenyl-3H-pyrrolo<1,2-a>indol-3-imin 
• 84211-60-9 3-Oxo-3-(4-oxo-cyclohexyl)-N-phenyl-2-(triphenyl-λ⁵-phosphanylidene)-propionamide 
• 3120-06-7 3-ethyl-1-phenyl-1H-pyrrole-2,5-dione 
• 75872-36-5 1-{4-Methoxy-1-phenyl-6-[(E)-phenylimino]-1,6-dihydro-pyridazin-3-yl}-ethanone 
• 75872-34-3 4-Methoxy-1-phenyl-6-[(E)-phenylimino]-1,6-dihydro-pyridazine-3-carboxylic acid methyl ester 
• 108159-93-9 [4-[(Z)-Phenylimino]-3-(triphenyl-λ⁵-phosphanylidene)-thietan-(2E)-ylideneamino]-acetic acid methyl ester 
• 75872-44-5 [5-[(E)-Cyclohexylimino]-4-phenyl-5H-thiophen-(2E)-ylidene]-phenyl-amine 
• 75509-03-4 N-(4-Methoxy-phenyl)-N'-[4-[(Z)-phenylimino]-3-(triphenyl-λ⁵-phosphanylidene)-thietan-(2Z)-ylidene]-benzamidine 
• 75508-97-3 1,1-Dicyclohexyl-3-[4-[(Z)-phenylimino]-3-(triphenyl-λ⁵-phosphanylidene)-thietan-(2Z)-ylidene]-urea 
• 84211-58-5 3-Oxo-4-(3-oxo-cyclopentyl)-N-phenyl-2-(triphenyl-λ⁵-phosphanylidene)-butyramide 
• 75872-46-7 [5-[(E)-Butylimino]-4-phenyl-5H-thiophen-(2E)-ylidene]-phenyl-amine 

Relevant articles and documents

Phosphane Alkylenes, 54. - Cumulated Ylides, 21. - A New Way to N-Substituted (Triphenylphosphoranylidene)ketenimines

Reaction of methylenetriphenylphosphorane (1) with isocyanates 5 leads to ylides 6B, which can be methylated at the S atom to give the phosphonium salts 8.Treatment of 8 with sodium methanolate gives rise to formation of the phosphoranes 10, which on treatment with sodium bis(trimethylsilyl)amide undergo β-elimination to form the N-substituted (triphenylphosphoranylidene)ketenimides 3.

Cumulated Ylides, IX. New Synthesis of N-substituted (Triphenylphosphoranylidene)ketenimines and (Triphenylphosphoranylidene)thioketene

Methylenetriphenylphosphorane (1) and isocyanidedichlorides resp. thiophosgene react in the molar ratio 3:1 to give N-substituted (triphenylphosphoranylidene)ketenimines 6A resp. (triphenylphosphoranylidene)thioketene 6B and methyltriphenylphosphonium chloride.The P-Cα-coupling constants in the 13C-NMR-spectra of 6 are in agreement with theoretical calculations.