64456-62-8

Basic information

• Product Name: Benzenamine, 4-bromo-N-cyclohexylidene-
• CAS NO: 64456-62-8
• Molecular Formula: C12H14BrN
• Molecular Weight: 252.154
• Mol File: 64456-62-8.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: Benzenamine, 4-bromo-N-cyclohexylidene-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenamine, 4-bromo-N-cyclohexylidene-(64456-62-8)
• EPA Substance Registry System: Benzenamine, 4-bromo-N-cyclohexylidene-(64456-62-8)

Safety Data

• Hazardous Substances Data: 64456-62-8(Hazardous Substances Data)

Upstream product

• 108-94-1 cyclohexanone 
• 106-40-1 4-bromo-aniline 
• 117781-60-9 (4-Bromo-phenyl)-cyclohex-1-enyl-amine 

Downstream Products

• 155557-65-6 N₄,N₄'-bis(4-aminophenyl)-N₄,N₄'-diphenyl-[1,1'-biphenyl]-4,4'-diamine 
• 113388-04-8 4-bromo-N-cyclohexylaniline 
• 54446-36-5 4-bromodiphenylamine 
• 142071-66-7 1-allyl-1-(p-bromophenylamino)cyclohexane 

Relevant articles and documents

Preparation method of OLED intermediate material terphenylamine derivative

The invention relates to a preparation method of an OLED intermediate material terphenylamine derivative. The method includes: taking compound A and 9-fluorenone or cyclohexanone as the raw materials, dissolving the raw materials in a benzene solvent, und

Synthesis of 3-Sulfonylamino Quinolines from 1-(2-Aminophenyl) Propargyl Alcohols through a Ag(I)-Catalyzed Hydroamination, (2 + 3) Cycloaddition, and an Unusual Strain-Driven Ring Expansion

We describe herein a silver-catalyzed conversion of 1-(2-aminophenyl)-propargyl alcohols to 4-substituted 3-tosylaminoquinolines using TsN3 as an amino surrogate. Controlled reactions reveal the pathway consisting of Ag(I)-catalyzed 5-exo-dig cyclization, catalyst-free (2 + 3) cycloaddition, and ring-expansive rearrangement via nitrogen expulsion. As a support study, we show that the cyclic enamines in similar conditions produce amidines via a C - C bond migration. (Chemical Equation Presented).