64472-71-5

Upstream product

• 1197-98-4 benzenesulfonyl thiocyanate 
• 98-09-9 benzenesulfonyl chloride 
• 873-55-2 sodium benzenesulfonate 
• 1515-79-3 5,5-dimethyl-1,3-hexadiene 
• 80129-19-7 ((E)-5,5-Dimethyl-4-thiocyanato-hex-2-ene-1-sulfonyl)-benzene 
• 75875-74-0 ((Z)-4-Chloro-5,5-dimethyl-hex-2-ene-1-sulfonyl)-benzene 

Relevant academic research and scientific papers

REACTION OF 1,3-DIENES WITH ARYLSULFONYL THIOCYANATES

At room temperature arylsulfonyl thiocyanates add to conjugated dienes with the formation of 1,4-addition products.In all cases the organic sulfonyl radical is fixed at the least substituted carbon atom of the 1,3-diene system.In reaction with triethylamine or sodium ethoxide the adducts which form eliminate thiocyanic acid with the formation of conjugated dienyl sulfones.