64504-73-0Relevant articles and documents
Black-light-induced radical/ionic hydroxymethylation of alkyl iodides with atmospheric co in the presence of tetrabutylammonium borohydride
Kobayashi, Shoji,Kawamoto, Takuji,Uehara, Shohei,Fukuyama, Takahide,Ryu, Ilhyong
supporting information; experimental part, p. 1548 - 1551 (2010/07/06)
(Figure Presented) Tin-free radical/ionic hydroxymethylation of secondary and tertiary alkyl iodides proceeded efficiently in the presence of tetrabutylammonium borohydride as the hydrogen source under atmospheric pressure of CO In conjunction with photoirradiation using black light. Two possible mechanisms were proposed, both of which involve hybrid radical/ionic processes.
X=Y-ZH Systems as potential 1,3-dipoles. Part 52: Fused-ring forming electrophile induced oxime→nitrone→cycloaddition cascades
Ali Dondas,Grigg, Ronald,Thibault, Sylvie
, p. 7035 - 7045 (2007/10/03)
Electrophile induced cyclisation of oximes onto endocyclic alkenes and exo-methylene cycloalkanes occurs stereo- and regio-specifically generating cis-fused bicyclic nitrones in good yield. Subsequent facially selective cycloaddition with N-methylmaleimid
