64519-41-1

Basic information

• Product Name: methyl 2,3,6-trideoxy-3-[(trifluoroacetyl)amino]hexopyranoside
• CAS NO: 64519-41-1
• Molecular Formula: C₉H₁₄F₃NO₄
• Molecular Weight: 257.207
• Mol File: 64519-41-1.mol
• Article Data: 3

Chemical Properties

• Boiling Point: 352.9°C at 760 mmHg
• Flash Point: 167.2°C
• Density: 1.33g/cm³
• Vapor Pressure: 2.16E-06mmHg at 25°C
• Refractive Index: 1.44
• CAS DataBase Reference: methyl 2,3,6-trideoxy-3-[(trifluoroacetyl)amino]hexopyranoside(CAS DataBase Reference)
• NIST Chemistry Reference: methyl 2,3,6-trideoxy-3-[(trifluoroacetyl)amino]hexopyranoside(64519-41-1)
• EPA Substance Registry System: methyl 2,3,6-trideoxy-3-[(trifluoroacetyl)amino]hexopyranoside(64519-41-1)

Safety Data

• Hazardous Substances Data: 64519-41-1(Hazardous Substances Data)

Upstream product

• 17016-62-5 methyl-3-acetamido-2,3,6-tridesoxy-α-D-arabino-hexopyranoside 
• 18933-62-5 methyl 3-azido-4-O-benzoyl-6-bromo-2,3,6-trideoxy-α-D-arabino-hexopyranoside 
• 67693-33-8 methyl-3-amino-2,3,6-tridesoxy-α-D-arabino-hexopyranoside 
• 407-25-0 trifluoroacetic anhydride 

Downstream Products

• 64429-67-0 N-((2R,3S,4R,6S)-3,6-Dihydroxy-2-methyl-tetrahydro-pyran-4-yl)-2,2,2-trifluoro-acetamide 
• 70629-87-7 7-O-(2,3,6-tridesoxy-4-O-p-nitrobenzoyl-3-trifluoroacetamido-β-D-arabino-hexopyranosyl)daunomycinone 
• 70629-86-6 7-O-(2,3,6-tridesoxy-4-O-p-nitrobenzoyl-3-trifluoroacetamido-α-D-arabino-hexopyranosyl)daunomycinone 
• 76753-25-8 2,3,6-tridesoxy-4-O-p-nitrobenzoyl-3-trifluoroacetamido-D-arabino-hexopyranose 
• 76793-37-8 1-O-acetyl-2,3,6-tridesoxy-4-O-p-nitrobenzoyl-3-trifluoroacetamido-β-D-arabino-hexopyranose 
• 76793-36-7 1-O-acetyl-2,3,6-tridesoxy-4-O-p-nitrobenzoyl-3-trifluoroacetamido-α-D-arabino-hexopyranose 
• 76753-26-9 methyl-2,3,6-tridesoxy-4-O-p-nitrobenzoyl-3-trifluoroacetamido-α-D-arabino-hexopyranoside 

Relevant articles and documents

Stereoselective reactions. XX. Synthetic studies on optically active β-lactams. III. Stereocontrolled synthesis of chiral intermediate to (+)-thienamycin from D-glucose

A chiral key intermediate (19a) for the synthesis of (+)-thienamycin was synthesized starting from D-glucose. The enol ether 13, obtained from the ketone 11 by Horner-Wittig reaction, was transformed to the corresponding methyl ester 16 by pyridinium chlorochromate oxidation or by employing the Wacker process. The ester 16 was further converted to the β-lactam 19a, which is a useful chiral precursor to (+)-thienamycin.

New daunorubicin analogs. 3-amino-2,3,6-trideoxy-α- and β-D-arabino- and 3,6-diamino-2,3,6-trideoxy-α-D-ribohexopyranosides of daunomycinone

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