70629-86-6

Basic information

• Product Name: 3-acetyl-3,5,12-trihydroxy-10-methoxy-6,11-dioxo-1,2,3,4,6,11-hexahydrotetracen-1-yl 2,3,6-trideoxy-4-O-(4-nitrobenzoyl)-3-[(trifluoroacetyl)amino]hexopyranoside
• CAS NO: 70629-86-6
• Molecular Formula: C₃₆H₃₁F₃N₂O₁₄
• Molecular Weight: 772.6315
• Mol File: 70629-86-6.mol
• Article Data: 2

Chemical Properties

• Boiling Point: 920.9°C at 760 mmHg
• Flash Point: 510.7°C
• Density: 1.61g/cm³
• Vapor Pressure: 0mmHg at 25°C
• Refractive Index: 1.656
• CAS DataBase Reference: 3-acetyl-3,5,12-trihydroxy-10-methoxy-6,11-dioxo-1,2,3,4,6,11-hexahydrotetracen-1-yl 2,3,6-trideoxy-4-O-(4-nitrobenzoyl)-3-[(trifluoroacetyl)amino]hexopyranoside(CAS DataBase Reference)
• NIST Chemistry Reference: 3-acetyl-3,5,12-trihydroxy-10-methoxy-6,11-dioxo-1,2,3,4,6,11-hexahydrotetracen-1-yl 2,3,6-trideoxy-4-O-(4-nitrobenzoyl)-3-[(trifluoroacetyl)amino]hexopyranoside(70629-86-6)
• EPA Substance Registry System: 3-acetyl-3,5,12-trihydroxy-10-methoxy-6,11-dioxo-1,2,3,4,6,11-hexahydrotetracen-1-yl 2,3,6-trideoxy-4-O-(4-nitrobenzoyl)-3-[(trifluoroacetyl)amino]hexopyranoside(70629-86-6)

Safety Data

• Hazardous Substances Data: 70629-86-6(Hazardous Substances Data)

Upstream product

• 34820-21-8 1,5-anhydro-3,4-di-O-benzoyl-2,6-didesoxy-L-arabino-hex-1-enitol 
• 76739-66-7 3,4-di-O-acetyl-D-rhamnal 
• 21794-55-8 (+)-Daunomycinone 
• 76793-36-7 1-O-acetyl-2,3,6-tridesoxy-4-O-p-nitrobenzoyl-3-trifluoroacetamido-α-D-arabino-hexopyranose 
• 72384-25-9 1,5-anhydro-2,3,6-tridesoxy-4-O-p-nitrobenzoyl-3-trifluoroacetamido-D-arabino-hex-1-enitol 
• 122-04-3 4-nitro-benzoyl chloride 
• 73891-04-0 2,3,6-tridesoxy-4-O-p-nitrobenzoyl-3-(trifluoroacetamido)-L-arabino-hex-1-enitol 
• 76753-26-9 methyl-2,3,6-tridesoxy-4-O-p-nitrobenzoyl-3-trifluoroacetamido-α-D-arabino-hexopyranoside 
• 76753-25-8 2,3,6-tridesoxy-4-O-p-nitrobenzoyl-3-trifluoroacetamido-D-arabino-hexopyranose 
• 73864-37-6 3-amino-1,5-anhydro-2,3,6-tridesoxy-D-arabino-hex-1-enitol 
• 67693-33-8 methyl-3-amino-2,3,6-tridesoxy-α-D-arabino-hexopyranoside 
• 64519-41-1 methyl-2,3,6-tridesoxy-3-trifluoroacetamido-α-D-arabino-hexopyranoside 
• 17016-62-5 methyl-3-acetamido-2,3,6-tridesoxy-α-D-arabino-hexopyranoside 
• 14218-08-7 2,3,4-tri-O-benzoyl-α-L-rhamnopyranosyl bromide 

Relevant articles and documents

HEMISYNTHESE DE NOUVEAUX GLICOSIDES ANALOGUES DE LA DAUNORUBICINE

Seven daunorubicin analogs containing α-L-, α-D-, and β-D-glicosidic linkages, in which the natural occuring sugar (L-daunosamine) was replaced by diastereomeric 3-amino-2,3,6-trideoxyhexoses (3-epi-L-daunosamine, D-acosamine, D-daunosamine, D-ristosamine, and 3-epi-D-daunosamine), were prepared.In all cases, glycosidation with daunomycinone was performed in the presence of p-toluenesulfonic acid starting from 1-O-acetyl-2,3,6-trideoxy-4-O-p-nitrobenzoyl-3-trifluoro-acetamidohexopyranoses (prepared from the corresponding methyl 3-amino-2,3,6-trideoxyhexopyranosides) or from 1,5-anhydro-2,3,6-trideoxy-4-O-p-nitrobenzoyl-3-trifluoroacetamidohex-1-enitols (prepared from glycosals or pseudoglycals, the 3-amino group being introduced by substitution with sodium azide and subsequent reduction).Glycosidation was followed by removal of the protecting groups.