64526-81-4

Upstream product

• 19465-06-6 methyl 4,6-O-benzylidene-2-deoxy-2-C-methyl-α-D-altropyranoside 
• 74-83-9 methyl bromide 
• 64526-80-3 methyl 4,6-O-benzylidene-2-deoxy-2-C-methyl-α-D-arabino-hexopyranoside 
• 4148-71-4 methyl (exo-Ph)-2,3: 4,6-di-O-benzylidene-α-D-mannopyranoside 
• 19465-06-6 methyl 4,6-O-benzylidene-2-deoxy-2-C-methyl-α-D-altro-pyranoside 
• 2880-96-8 methyl 2,3-anhydro-4,6-O-benzylidene-α-D-allopyranoside 

Downstream Products

• 75879-81-1 Methyl 4,6-O-Benzylidene-2-deoxy-2-C-methyl-α-D-allopyranoside 
• 82707-03-7 (2S,4S,5R,6S)-2-(tert-Butyl-diphenyl-silanyloxymethyl)-6-methoxy-5-methyl-3-methylene-tetrahydro-pyran-4-ol 
• 100-52-7 benzaldehyde 
• 64526-82-5 methyl 4,6-O-benzylidene-2-deoxy-2-C-methyl-3-O-methyl-α-D-allopyranoside 
• 82707-13-9 methyl 3-O-acetyl-4,6-O-benzylidene-2-C-methyl-α-D-allopyranoside 
• 82707-07-1 methyl 2,4-dideoxy-2-C-methyl-3-O-methyl-6-O-triphenylmethyl-α-D-xylo-hexopyranoside 
• 82707-17-3 methyl 4-chloro-2,4-dideoxy-2-C-methyl-3-O-methyl-6-O-triphenylmethyl-α-D-galactopyranoside 
• 82707-02-6 Acetic acid (2S,4S,5R,6S)-2-(tert-butyl-diphenyl-silanyloxymethyl)-6-methoxy-5-methyl-3-methylene-tetrahydro-pyran-4-yl ester 
• 82731-51-9 methyl 3-O-acetyl-6-O-t-butyldiphenylsilyl-2-deoxy-C-methyl-α-D-allopyranoside 
• 82731-52-0 methyl 3-O-acetyl-6-O-t-butyldiphenylsilyl-2-deoxy-2-C-methyl-α-D-ribo-hexapyranoside-3-ulose 
• 92268-68-3 ((2S,3R,4R,5R,6S)-4-Benzyloxy-6-methoxy-3,5-dimethyl-tetrahydro-pyran-2-yl)-{2-[(1R,2S)-3-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-2-methoxy-1-methyl-propyl]-[1,3]dithian-2-yl}-methanone 
• 82707-09-3 (2S,3S,4R,6R,7S,8S,9S)-3-Benzyloxy-10-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-7-hydroxy-9-methoxy-2,4,6,8-tetramethyl-1-trityloxy-decan-5-one 
• 82707-09-3 (2S,3S,4R,6S,7R,8S,9S)-3-Benzyloxy-10-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-7-hydroxy-9-methoxy-2,4,6,8-tetramethyl-1-trityloxy-decan-5-one 
• 92232-36-5 methyl 2-deoxy-2-C-methyl-3-O-methyl-6-O-triphenylmethyl-α-D-glucopyranoside 

Relevant academic research and scientific papers

An Approach to the Total Synthesis of the Prelog-Djerassi Lactone

An approach to the synthesis of the Prelog-Djerassi lactone using D-glucose as a starting material is described.The use of Swern oxidation provides an efficient means of preparing carbohydrate ketones.An unusual departure from the normal reaction pathway

ASSEMBLY OF THE C19-C29 ALIPHATIC SEGMENT OF RIFAMYCIN S FROM D-DLUCOSE BY THE CHIRON APPROACH

We describe a stereocontrolled method for the construction of the aliphatic chain of rifamycin S, based on a strategy that utilizes carbohydrates as optically active precursors.

A Short Route to 2-C-Alkyl-2-deoxy-sugars from D-Mannose

The lithium enolate (2), readily obtained from the D-mannose derivative (1) at low temperature, reacts with electrophilic reagents in a tetrahydrofuran-hexamethylphosphoric triamide mixture, providing a short route to 2-C-alkyl sugars; the subsequent enol