64526-84-7

Upstream product

• 64526-81-4 methyl 4,6-O-benzylidene-2-deoxy-2-C-methyl-α-D-ribo-hexopyranoside 
• 64526-80-3 methyl 4,6-O-benzylidene-2-deoxy-2-C-methyl-α-D-arabino-hexopyranoside 
• 64526-83-6 methyl 2-deoxy-2-C-methyl-3-O-methyl-6-O-triphenylmethyl-α-D-allopyranoside 
• 64526-82-5 methyl 4,6-O-benzylidene-2-deoxy-2-C-methyl-3-O-methyl-α-D-allopyranoside 
• 75879-81-1 Methyl 4,6-O-Benzylidene-2-deoxy-2-C-methyl-α-D-allopyranoside 
• 19465-06-6 methyl 4,6-O-benzylidene-2-deoxy-2-C-methyl-α-D-altro-pyranoside 
• 92232-35-4 (2R,3S,4S,5R,6S)-2-Hydroxymethyl-4,6-dimethoxy-5-methyl-tetrahydro-pyran-3-ol 

Downstream Products

• 92232-36-5 methyl 2-deoxy-2-C-methyl-3-O-methyl-6-O-triphenylmethyl-α-D-glucopyranoside 
• 82707-09-3 (2S,3S,4R,6S,7R,8S,9S)-3-Benzyloxy-10-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-7-hydroxy-9-methoxy-2,4,6,8-tetramethyl-1-trityloxy-decan-5-one 
• 82707-09-3 (2S,3S,4R,6R,7S,8S,9S)-3-Benzyloxy-10-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-7-hydroxy-9-methoxy-2,4,6,8-tetramethyl-1-trityloxy-decan-5-one 
• 92268-68-3 ((2S,3R,4R,5R,6S)-4-Benzyloxy-6-methoxy-3,5-dimethyl-tetrahydro-pyran-2-yl)-{2-[(1R,2S)-3-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-2-methoxy-1-methyl-propyl]-[1,3]dithian-2-yl}-methanone 
• 82707-17-3 methyl 4-chloro-2,4-dideoxy-2-C-methyl-3-O-methyl-6-O-triphenylmethyl-α-D-galactopyranoside 
• 64526-85-8 methyl 2-deoxy-2-C-methyl-3-O-methyl-6-O-triphenylmethyl-α-D-xylo-hexapyranosid-4-ulose 
• 64526-83-6 (2R,4R,5R,6S)-4,6-Dimethoxy-5-methyl-2-trityloxymethyl-tetrahydro-pyran-3-ol 
• 82707-09-3 (2S,3S,4R,8S,9S)-3-Benzyloxy-10-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-7-hydroxy-9-methoxy-2,4,6,8-tetramethyl-1-trityloxy-decan-5-one 
• 82707-10-6 (2S,3S,6S,7S,8S,9S)-8-Benzyloxy-1-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-2-methoxy-3,5,7,9-tetramethyl-10-trityloxy-decane-4,6-diol 
• 82707-17-3 (2R,4R,5R,6S)-3-Chloro-4,6-dimethoxy-5-methyl-2-trityloxymethyl-tetrahydro-pyran 
• 82707-07-1 methyl 2,4-dideoxy-2-C-methyl-3-O-methyl-6-O-triphenylmethyl-α-D-xylo-hexopyranoside 

Relevant academic research and scientific papers

ASSEMBLY OF THE C19-C29 ALIPHATIC SEGMENT OF RIFAMYCIN S FROM D-DLUCOSE BY THE CHIRON APPROACH

We describe a stereocontrolled method for the construction of the aliphatic chain of rifamycin S, based on a strategy that utilizes carbohydrates as optically active precursors.