64543-64-2Relevant academic research and scientific papers
Catalytic scope of the thiamine-dependent multifunctional enzyme cyclohexane-1,2-dione hydrolase
Loschonsky, Sabrina,Waltzer, Simon,Fraas, Sonja,Wacker, Tobias,Andrade, Susana L. A.,Kroneck, Peter M. H.,Mueller, Michael
, p. 389 - 392 (2014/03/21)
The thiamine diphosphate (ThDP)-dependent enzyme cyclohexane-1,2-dione hydrolase (CDH) was expressed in Escherichia coli and purified by affinity chromatography (Ni-NTA). Recombinant CDH showed the same Ci£C bond-cleavage and Ci£C bond-formation activitie
Nucleophilic acylation of esters by acid chlorides mediated by samarium diiodide: Formation and use of samarium enediolates.
Machrouhi, Fouzia,Namy, Jean-Louis,Kagan, Henri B.
, p. 7183 - 7186 (2007/10/03)
Acid chlorides react with esters in the presence of samarium diiodide and catalytic amounts of NiI2 to afford samarium enediolates which can further react with electrophiles such as water or aldehydes to give respectively α-ketols or α-dihydroxyketones.
