64566-29-6Relevant academic research and scientific papers
A Direct Retro-Reformatsky Fragmentation: Formal Ring Enlargement of Cyclic Ketones for Novel and Practical Synthesis of Heterocyclic Enamines
Zhao, Mei-Xin,Wang, Mei-Xiang,Yu, Chu-Yi,Huang, Zhi-Tang,Fleet, George W. J.
, p. 997 - 1000 (2004)
A novel and practical synthesis of heterocyclic enamines has been developed from the formal ring enlargement of cyclic ketones, which comprised the retro-Reformatsky fragmentation reaction as a key step. Under alkaline bromination conditions, the Reformat
A New, General Cyclopentenone Synthesis
Ceccherelli, Paolo,Curini, Massimo,Marcotullio, Maria Carla,Rosati, Ornelio,Wenkert, Ernest
, p. 311 - 315 (2007/10/02)
A new synthesis of cyclopentenones, involving an Rh(II)-catalyzed, intramolecular carbon-hydrogen insertion of diazomethyl ketones derived from α,β-unsaturated acids, is described.
