6460-44-2Relevant academic research and scientific papers
Kinetics and mechanism of pyridinolyses of aryl methyl and aryl propyl chlorothiophosphates in acetonitrile
Barai, Hasi Rani,Lee, Hai Whang
, p. 483 - 488 (2014/03/21)
The nucleophilic substitution reactions of Y-aryl methyl (8) and Y-aryl propyl (10) chlorothiophosphates with X-pyridines are studied kinetically in acetonitrile at 35.0 °C. The Hammett and Broensted plots with X in the nucleophiles for both substrates ex
A new convenient synthesis of phosphoro(-no)chloridothionates
He, Zheng-Jie,Liu, Ju-Xiang,Tang, Chu-Chi
, p. 2769 - 2772 (2007/10/03)
A general procedure for synthesis of phosphoro(-no)chlorides, particularly unsymmetrical ones, has been developed. The method involves the dealkylation of O,O-dialkyl phosphoro(-no)thionates 1 with dimethylamine and the chlorination of O-alkyl ammonium phosphoro(-no)thioates 2 using phosphorus oxychloride as a chlorinating agent.
Stereochemistry of Aryl Methyl Phosphorochloridothionates as Chiral Two-step Phosphorylating Reagents
Shao-Yong, Wu,Eto, Morifusa
, p. 3071 - 3080 (2007/10/02)
Seven aryl methyl phosphorochloridothionates were prepared and examined for reactivity as two-step phosphorylating reagents to synthesize oxazaphospholidine sulfide.The 2,6-dichloro-4-methylphenyl and p-nitrophenyl derivatives (CMPC and MNPC) were selecte
