646030-55-9

Upstream product

• 501015-40-3 (2S,3S)-(+)-toluene-4-sulfonic acid 3-hydroxy-2-methylhex-5-enyl ester 
• 501015-43-6 (2S,3S)-2-allyl-5-benzenesulfonyl-3-methyltetrahydrofuran 
• 501015-41-4 (3S,4S)-(+)-1-cyano-4-hydroxy-3-methylhept-6-ene 
• 501015-54-9 (2S,3S,4R,2'R,4'S,5'S)-(-)-1-(5-allyl-4-methyltetrahydrofuran-2-yl)-5-(tert-butyldimethylsilanyloxy)-3-methoxymethoxy-4-methylpentan-2-ol 
• 501015-53-8 (3S,4R,2'R,4'S,5'S)-(-)-1-(5-allyl-4-methyltetrahydrofuran-2-yl)-5-(tert-butyldimethylsilanyloxy)-3-methoxymethoxy-4-methylpentan-2-one 
• 501015-49-2 (3S,4R)-(-)-2,5-bis(tert-butyldimethylsilanyloxy)-3-methoxymethoxy-4-methylpent-1-ene 
• 501015-45-8 (2'S,3'R,4S,5R)-(-)-3-(3-methoxymethoxy-2,4-dimethylpent-4-enoyl)-4-methyl-5-phenyloxazolidin-2-one 
• 501015-44-7 (2'S,3'R,4S,5R)-(-)-3-(3-hydroxy-2,4-dimethylpent-4-enoyl)-4-methyl-5-phenyloxazolidin-2-one 
• 501015-48-1 (3S,4R)-(-)-5-(tert-butyldimethylsilanyloxy)-3-methoxymethoxy-4-methylpentan-2-one 
• 501015-47-0 (2R,3S)-(-)-tert-butyl-(3-methoxymethoxy-2,4-dimethylpent-4-enyloxy)dimethylsilane 
• 501015-46-9 (2R,3S)-(-)-3-methoxymethoxy-2,4-dimethylpent-4-en-1-ol 
• 646030-69-5 (2R,3S,4S,2'R,4'S,5'S)-(-)-[5-(5-allyl-4-methyltetrahydrofuran-2-yl)-4-(4-methoxybeznyloxy)-3-methoxymethoxy-4-methylpentyloxy]tert-butyldimethylsilane 

Relevant academic research and scientific papers

Total Syntheses of Amphidinolide T1, T3, T4, and T5

A concise, flexible, and high yielding entry into the family of amphidinolide T macrolides, a series of cytotoxic natural products of marine origin, has been developed. All individual members, except amphidinolide T3 (3), derive from compound 39 as a comm

Total synthesis of amphidinolide T4

Organometallic chemistry in general and catalysis in particular are used in the first total synthesis of amphidinolide T4 (see scheme); a prototype member of a series of macrolide antibiotics of marine origin with rings containing an odd number of carbon