646036-41-1Relevant articles and documents
Enantioselective Desymmetrization of Tropinone Derivatives by Hydroboration
Cramer, Nicolai,Laschat, Sabine,Baro, Angelika,Frey, Wolfgang
, p. 2175 - 2177 (2007/10/03)
N-Protected tropenone derivatives 3, prepared from the respective pyrroles 5 and tetrabromoacetone (6), were used as starting materials for desymmetrization by hydroboration of the C-C double bond. Hydroboration of 3a with (-)-(Ipc)2BH followed