64630-89-3

Basic information

• Product Name: DL-dicyclohexyl (1R,2R,3S,4S)-3,4-diphenylcyclobutane-1,2-dicarboxylate
• Synonyms: DL-dicyclohexyl (1R,2R,3S,4S)-3,4-diphenylcyclobutane-1,2-dicarboxylate
• CAS NO: 64630-89-3
• Molecular Weight: 460.613
• Mol File: 64630-89-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: DL-dicyclohexyl (1R,2R,3S,4S)-3,4-diphenylcyclobutane-1,2-dicarboxylate(CAS DataBase Reference)
• NIST Chemistry Reference: DL-dicyclohexyl (1R,2R,3S,4S)-3,4-diphenylcyclobutane-1,2-dicarboxylate(64630-89-3)
• EPA Substance Registry System: DL-dicyclohexyl (1R,2R,3S,4S)-3,4-diphenylcyclobutane-1,2-dicarboxylate(64630-89-3)

Safety Data

• Hazardous Substances Data: 64630-89-3(Hazardous Substances Data)

Upstream product

• 7779-17-1 (E)-cyclohexyl cinnamate 
• 140-10-3 (E)-3-phenylacrylic acid 
• 904825-05-4 δ-Truxinicacid 
• 108-93-0 cyclohexanol 

Relevant articles and documents

General and Efficient Intermolecular [2+2] Photodimerization of Chalcones and Cinnamic Acid Derivatives in Solution through Visible-Light Catalysis

[2+2] Photocycloaddition, for example, the dimerization of chalcones and cinnamic acid derivatives, is a unique strategy to construct cyclobutanes, which are building blocks for a variety of biologically active molecules and natural products. However, most attempts at the above [2+2] addition have focused on solid-state, molten-state, or host–guest systems under ultraviolet-light irradiation in order to overcome the competition of facile geometric isomerization of nonrigid olefins. We report a general and simple method to realize the intermolecular [2+2] dimerization reaction of these acyclic olefins to construct cyclobutanes in a highly regio- and diastereoselective manner in solution under visible light, which provides an efficient solution to a long-standing problem.