646523-38-8Relevant articles and documents
Piperazine additions to C60 - A facile approach to fullerene substitution
Butts, Craig P.,Jazdzyk, Mikael D. S.
, p. 1209 - 1215 (2007/10/03)
A range of fullerene monoadducts can be generated via the photochemical reaction of piperazine derivatives with C60. Addend functionality can also be efficiently incorporated by transformation of the hydroxyl-substituted adduct prepared in this fashion. Reaction yields and process simplicity compete with current standard procedures for fullerene mono-functionalisation. The Royal Society of Chemistry 2005.
The preparation and structures of non-hydrocarbon functionalised fullerene-diamine adducts
Butts, Craig P.,Jazdzyk, Mikael
, p. 1530 - 1531 (2007/10/03)
Addends based on C2-substituted piperazine are employed to generate C60 monoadducts by photochemical addition, representing the first introduction of non-hydrocarbon addend functionality to fullerenes via the oxidative dehydrogenation reaction of diamines with fullerenes.