64668-09-3Relevant academic research and scientific papers
Synthesis, characterization, and catalytic activity of cationic NHC gold(III) pyridine complexes
Orbisaglia, Serena,Jacques, Beatrice,Braunstein, Pierre,Hueber, Damien,Pale, Patrick,Blanc, Aurelien,De Fremont, Pierre
, p. 4153 - 4164 (2013)
A series of cationic gold(I/III) pyridine complexes of the type [(L)Au(pyr)](PF6) and [(L)AuCl2(pyr)](PF6), where L = IPr, (1, 5); L = IMes (2, 6); L = ItBu, (3, 7); L = ICy (4, 8); and L = PPh3, (9, 10), were synthesized and characterized by NMR spectroscopy and single-crystal X-ray diffraction. The stability of the new complexes and their catalytic activity in five well-established organic transformations were assessed.
