64668-60-6

Upstream product

• 7601-90-3 perchloric acid 
• 1166987-51-4 Mn(C₃H₂(Au(P(C₆H₅)3))NO)(CO)3(C₅H₄N)2⁽¹⁺⁾ 
• 1166987-53-6 Mn(C₃H₂(Au(P(C₆H₅)3))NS)(CO)3(C₅H₄N)2⁽¹⁺⁾ 

Downstream Products

• 112079-37-5 fac-{Mn(PHPh₂)(CO)3(2.2'-bipyridine)}ClO₄ 
• 80678-53-1 fac-{Mn(CO)3(bipy)(dppm)}ClO₄ 
• 103902-99-4 fac-Mn(2,2′-bipyridyl)(CO)₃(CCPh) 
• 79982-35-7 cis,trans-{Mn(CO)2(bipy)(P(OEt)2Ph)2}ClO₄ 

Relevant academic research and scientific papers

NHC-manganese(i) complexes as carbene transfer agents

Tautomerization of coordinated azoles to their corresponding N-heterocyclic carbenes (NHCs) has been carried out by reaction of complexes fac-[Mn(L)(CO)3(dppe)]+ (L = N-phenylimidazole) and fac-[Mn(L)(CO)3(bipy)]+/su

Metal-induced tautomerization of oxazole and thiazole molecules to heterocyclic carbenes

Oxazole and thiazole molecules N-coordinated to manganese(i) are transformed into their corresponding 2,3-dihydrooxazol-2-ylidene and 2,3-dihydrothiazol-2-ylidene carbene tautomers by acid-base reactions, and subsequently transmetalated to gold(i), via is

Base-promoted tautomerization of imidazole ligands to N-heterocyclic carbenes and subsequent transmetalation reaction

Imidazole complexes of manganese(I) are transformed into their corresponding N-heterocyclic carbene derivatives by means of acid-base treatments; the subsequent sequential transmetalation reaction of the carbene to gold(I) proceeds through isolable hetero