64687-96-3Relevant academic research and scientific papers
COMPOUNDS, COMPOSITIONS, AND METHODS FOR MODULATING SWEET TASTE
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Paragraph 0306; 0311, (2014/10/04)
The present invention provides edible compositions comprising a sweet taste modulator of the present invention, food products comprising such edible compositions and methods of preparing such food products. The present invention also provides methods of reducing the amount of sugar in a food product, methods of reducing the caloric intake in a diet, and methods of enhancing sweet taste in a food product.
Acid catalyzed stereoselective rearrangement and dimerization of flavenes: synthesis of dependensin
Deodhar, Mandar,Black, David StC,Kumar, Naresh
, p. 5227 - 5235 (2008/02/01)
Appropriately substituted flavenes undergo stereoselective rearrangement and dimerization when treated with methanolic hydrochloric acid to give benzopyranobenzopyrans. A rationale for the rearrangement is proposed. This synthetic methodology has been used for a high yield synthesis of the natural product dependensin.
Synthesis of hydroxyflavanones from substituted acetophenones and benzaldehydes in the presence of silica gel, boric acid and piperidine
Zhang, Wei Han,Chan, Wing Lai,Lin, Yuan Hua,Szeto, Yau Shan,Lin, Yong Cheng,Yeung, Chi Hung
, p. 71 - 75 (2007/10/03)
Direct synthesis of hydroxyflavanones from appropriately substituted acetophenones and benzaldehydes was achieved in the presence of boric acid, silica gel and piperidine. The formation of flavanones presumably involved the reaction between the acetopheno
Metabolism of 2',4,4'-Trihydroxychalcone in Amorpha fruticosa Seedlings; Structure and Role of Chalaurenol, a Novel Heterocyclic Enol Ether formed by Enzymic Oxidation
Begley, Michael J.,Crombie, Leslie,London, A. Martin,Savin, John,Whiting, Donald A.
, p. 2775 - 2782 (2007/10/02)
Amorpha fruticosa seedlings contain two enzymes capable of catalysing reactions of 2',4,4'-trihydroxychalcone.One is a chalcone-flavanone isomerase, which has been purified and occurs as two isozymes.More interestingly, the second is a peroxidase, which oxidises the chalcone (1; R1 = R2 = OH, R3 = H) to a novel labile quinol enol ether, chalaurenol (6), whose structure is established by chemical studies and X-ray diffraction of the 6-O-methyl ether (5).The possible origins and role of chalaurenol in plant metabolism are discussed.
HETEROCYCLES. XIX. REACTION OF 2'-HYDROXYCHALCONES WITH ALKALINE HYDROGEN PEROXIDE
Takahashi, Hiroshi,Kubota, Yumiko,Fang, Lin,Onda, Masayuki
, p. 1099 - 1107 (2007/10/02)
Reaction of 2'-hydroxychalcones, which contain the hydroxyl and/or the methoxyl group at the 4- and 6'-positions, with alkaline hydrogen peroxide has been examined.It is observed that these substituents intricately influence the formation of the products.
Synthesis of (+/-)-Fistacacidin
Patil, A. D.,Deshpande, V. H.
, p. 109 - 113 (2007/10/02)
Synthesis of fistacacidin and (+/-)-2,3-trans-5,4'-dimethoxyflavan-3-ol (XVII) are reported.Synthesis of XII, starting from monobenzyl ether of 2,6-dihydroxyacetophenone (I) involves the reacti
