64701-55-9Relevant academic research and scientific papers
Synthesis of α-oxygenated β,γ-unsaturated ketones by a catalytic rearrangement strategy
Lempenauer, Luisa,Soupart, Aline,Du?ach, Elisabet,Lemière, Gilles
supporting information, p. 5441 - 5445 (2018/08/12)
A straightforward two-step entry to α-oxgenated β,γ-unsaturated ketones from readily available α,β-unsaturated ketones is disclosed. It was found that bis(allylic) alcohols undergo a skeletal rearrangement in the presence of 1 mol% of cheap and non-corros
Highly Regio- and Stereoselective 1,4-Addition Reaction of β-Cyclopropyl-α,β-enones with Organocopper(I)-Aluminum Trichloride
Ibuka, Toshiro,Tabushi, Eiji,Yasuda, Masahiro
, p. 128 - 134 (2007/10/02)
A highly regio- and stereoselective 1,4-addition reaction of β-cyclopropyl-α,β-enones with an equimolar mixture of organocopper(I) and aluminum trichloride (RCu-AlCl3) is described. Keywords ----- cyclopropylenone; conjugate addition; organometallic; stereoselectivity; regioselectivity; organocopper(I)-aluminum trichloride complex
