64714-85-8Relevant articles and documents
Synthesis of the Sex Pheromone of the Oleander Scale (Aspidiotus nerii)
Casta?eda, Mary Monta?o,Bargues, Javier Marzo,Primo, Jaime,Fuertes, Ismael Navarro
, p. 8578 - 8588 (2019/09/04)
A total synthesis of the oleander scale [Aspidiotus nerii (Bouche)] sex pheromone, the unique sesquiterpenoid containing a cyclobutane moiety of this class of compounds, has been developed. In order to implement this sex pheromone as a new environmentally
6-(2-Haloethyl)-2,2-dimethyl-4H-1,3-dioxins: versatile haloethyl vinyl ketone equivalents for carbocycle construction
Greshock, Thomas J.,Funk, Raymond L.
, p. 5437 - 5439 (2007/10/03)
6-(2-Iodoethyl)-2,2-dimethyl-4H-1,3-dioxin has been prepared in five steps from ethyl acetoacetate. A variety of enolates were then alkylated with this iodide. The resulting 6-alkyl-4H-1,3-dioxins were either subjected to further transformations and/or he
Condensation of Diethyl Acetonedicarboxylate. IV. Regioselective Reaction of Diethyl Acetonedicarboxylate-magnesium Complex
Yamato, Masatoshi,Kusunoki, Youichiro
, p. 2832 - 2836 (2007/10/02)
The reactivity of diethyl acetonedicarboxylate (DADC)-magnesium complex (1a, b) was examined.The Michael reaction of 1a, b gave the regioselectively monoalkylated derivative (2 or 3) of DADC.Reaction of 1a with nucleophilic reagents, LiAlH4 or alkylamines