64726-28-9

Upstream product

• 98-19-1 5-tert-Butyl-m-xylene 
• 2359-09-3 5-t-butylisophthalic acid 
• 22157-91-1 1,3-bis(hydroxymethyl)-5-tert-butylbenzene 

Downstream Products

• 154742-95-7 (3-{[Bis-(2-pyridin-2-yl-ethyl)-amino]-methyl}-5-tert-butyl-benzyl)-bis-(2-pyridin-2-yl-ethyl)-amine 
• 126694-82-4 5-tert-Butyl-N-(p-tolylsulfonyl)-1-thia-10-aza<2.2>metacyclophan 
• 126694-81-3 5-tert-Butyl-N-(p-tolylsulfonyl)-1-thia-10-aza<2.2>metacyclophan 
• 76447-63-7 (3-tert-butyl-5-sulfanylmethylphenyl)methanethiol 
• 156783-43-6 3-tert-butyl-1,5-bis((dimethylamino)methyl)benzene 
• 307310-83-4 3-(5-{3-tert-butyl-5-[5-(2-cyano-ethylsulfanyl)-4',5'-bis-methylsulfanyl-[2,2']bi[[1,3]dithiolylidene]-4-ylsulfanylmethyl]-benzylsulfanyl}-4',5'-bis-methylsulfanyl-[2,2']bi[[1,3]dithiolylidene]-4-ylsulfanyl)-propionitrile 
• 551943-09-0 1,3-bis(4'-formyl-2'-methoxyphenoxymethyl)-5-tert-butylbenzene 
• 222405-69-8 C₃₄H₅₄N₄ 
• 551943-11-4 1,3-bis(4'-hydroxymethyl-2'-methoxyphenoxymethyl)-5-tert-butylbenzene 
• 1056547-91-1 (3-(bromomethyl)-5-tert-butylbenzyl)(trityl)sulfane 
• 1056547-87-5 (5-tert-butyl-1,3-phenylene)bis(methylene)bis(benzylsulfane) 
• 1352833-79-4 C₈₂H₉₄S₈ 
• 1352833-76-1 C₅₄H₅₄S₄ 
• 1352833-77-2 C₃₅H₄₀S₄ 

Relevant academic research and scientific papers

Synthesis, characterization, and polymerization of capped paddlewheel porous cages

Although paddlewheel-based structures are common among permanently porous metal-organic materials, suitable strategies for the isolation of metal node-terminated, capped paddlewheel-based cage structures remain limited. We explored the use of chelating dicarboxylate ligand derivates (esp) for the isolation of trimesate-linked cages, Mo12(btc)4(esp)6, that are structural analogs of the small octahedral pore of HKUST-1. The porosity of these novel cages is appreciably higher than that of previously reported structures of this type. We also demonstrate that pillaring the isolated cage with DABCO generated an amorphous polymer that featured exceptional thermal stability and enhanced porosity.

COMPOUNDS FOR THE TREATMENT OF BACTERIAL INFECTIONS AND POTENTIATION OF ANTIBIOTICS

Compounds and methods for use to treat a bacterial infection caused by, for example, gram positive bacteria, gram negative bacteria, and/or mycobacteria are provided herein. Also provided herein are compounds and methods for use in potentiating the effect of an antibiotic in the treatment of a bacterial infection. Pharmaceutical compositions including the compounds as described herein are also provided.

AMIDINES AND AMIDINE ANALOGS FOR THE TREATMENT OF BACTERIAL INFECTIONS AND POTENTIATION ANTIBIOTICS

Compounds and methods for the treatment of a bacterial infection or the potentiation of an antibiotic in treating a bacterial infection are described herein.

Synthesis and conformational analysis of 2,11-dioxa[3.3]metacyclophanes

Synthesis and conformational analysis of three members of the dioxa[3.3]metacyclophane family were carried out. Variable-temperature 1H NMR spectroscopy was employed to show that three substances exist as equilibrium mixtures of syn and anti conformers in ratios that depend on the nature of arene ring substituent, temperature, and solvent. The findings are explained in terms of thermodynamic parameters and dipole moments of the metacyclophanes.

Heterophane prototypes containing azolium and/or azole anion-binding motifs

Revisiting a '3 + 1' convergent stepwise strategy permitted the synthesis of [14]imidazoliophane 2·2Br in excellent yield for a macrocyclization. The new [14]triazoliophane 3 and bis(1,2,3-triazolium) counterpart 4·2Cl were less synt

Gold nanoparticles stabilized by thioether dendrimers

Ligand-stabilized gold nanoparticles (Au NPs) are promising materials for nanotechnology with applications in electronics, catalysis, and sensors. These applications depend on the ability to synthesize stable and monodisperse NPs. Herein, the design and s

Synthesis of 8-methyl[2.2]metacyclophanes and their charge-transfer complexes with tetracyanoethylene

The regioselective 1:1 charge-transfer band of 13-substituted 8-methyl[2.2]metacyclophanes with tetracyanoethylene in CH2Cl 2, attributable to the 8-methyl substituted benzene-site complex, are observed in the field of 556-605 nm, which is strongly affected by π-electron density of the opposite aromatic ring.

Multidentate thioether ligands coating gold nanoparticles

The design and synthesis of oligomeric ligands based on benzylic thioethers is presented together with their ability to enwrap and stabilize gold nanoparticles with diameters below 2 nm, which become - with increasing length of the oligomer - more monodisperse and stable. The Royal Society of Chemistry.

A rigid sublimable naphthalenediimide cyclophane as model compound for UHV STM experiments

The design, synthesis and characterization of a rigid naphthalenediimide cyclophane as a model compound for ultrahigh vacuum (UHV) STM experiments are described together with first self-assembly investigations on an Au(111) substrate displaying the format

Anion binding versus intramolecular hydrogen bonding in neutral macrocyclic amides

Although amide groups are important hydrogen-bond donors in natural and synthetic anion receptors, studies on structure-affinity relationships of amide-based macrocyclic receptors are still very limited. Therefore, we synthesized a series of macrocyclic t