64732-75-8Relevant academic research and scientific papers
Reaction of (α-Thioalkyl)chromium Compounds Prepared by Chromium(II) Reduction of α-Halo Sulfides
Nakatsukasa, Shigeki,Takai, Kazuhiko,Utimoto, Kiitiro
, p. 5045 - 5046 (2007/10/02)
Reduction of α-chloroalkyl phenyl (or methyl) sulfides with chromium(II) chloride in THF proceeds smoothly in the presence of LiI.The resulting (α-thioalkyl)chromium reagents add to aldehydes in a chemo- and stereoselective manner.
HIGHLY STEREOSELECTIVE REDUCTION OF α-METHYLTHIO AND α-PHENYLTHIO KETONES---SYNTHESIS OF syn- AND anti-β-METHYLTHIO- AND β-PHENYLTHIOALCOHOLS---
Shimagaki, Masayuki,Maeda, Tadashi,Matsuzaki, Yuji,Hori, Ishaburo,Nakata, Tadashi,Oishi, Takeshi
, p. 4775 - 4778 (2007/10/02)
Reduction of α-methylthio and α-phenylthio ketones 1 with L- selectride gave syn-alcohols 2 in high stereoselectivity except when R1 was cyclohexyl group, while reduction with Zn(BH4)2 gave the isomeric anti-alcohols 3 provided R3 was a methyl group.
