64754-68-3Relevant academic research and scientific papers
Transfer Hydro-dehalogenation of Organic Halides Catalyzed by Ruthenium(II) Complex
You, Tingjie,Wang, Zhenrong,Chen, Jiajia,Xia, Yuanzhi
, p. 1340 - 1346 (2017/02/10)
A simple and efficient Ru(II)-catalyzed transfer hydro-dehalogenation of organic halides using 2-propanol solvent as the hydride source was reported. This methodology is applicable for hydro-dehalogenation of a variety of aromatic halides and α-haloesters and amides without additional ligand, and quantitative yields were achieved in many cases. The potential synthetic application of this method was demonstrated by efficient gram-scale transformation with catalyst loading as low as 0.5 mol %.
Stereoconvergent amine-directed alkyl-alkyl Suzuki reactions of unactivated secondary alkyl chlorides
Lu, Zhe,Wilsily, Ashraf,Fu, Gregory C.
supporting information; experimental part, p. 8154 - 8157 (2011/07/08)
A new family of stereoconvergent cross-couplings of unactivated secondary alkyl electrophiles has been developed, specifically, arylamine-directed alkyl-alkyl Suzuki reactions. This represents the first such investigation to be focused on the use of alkyl
A New and Practical Synthesis of Indolones
Boivin, Jean,Yousfi, Mohammed,Zard, Samir Z.
, p. 9553 - 9556 (2007/10/02)
A variety of indolones can be obtained from α-haloanilides through a radical cyclisation mediated by a combination of nickel powder and acetic acid.
