64770-16-7Relevant academic research and scientific papers
Synthesis of functionalized 1-substituted alkenylsilanols and establishment of conditions for their palladium-catalyzed cross-coupling reactions to afford 1-substituted styrene derivatives
Ghosh, Sunil K.,Singh, Rekha,Singh, Gobind C.
, p. 4141 - 4147 (2007/10/03)
An efficient method for the quantitative conversion of 1-substituted alkenyl(phenyl)silanes into the corresponding alkenylsilanols has been developed and used in their palladium(0)-catalyzed, tetrabutylammonium fluoride-promoted cross-coupling reaction wi
Ketene. Part 21. Reactions of Heterocumulenes with Nitrones
Evans, Andrew R.,Hafiz, Mushtaq,Taylor, Giles A.
, p. 1241 - 1246 (2007/10/02)
Degradative and mass spectrometric evidence confirms the formation of the isoxazolidinones (2) from the reaction of cyano-t-butylketene with the N-alkyl nitrones (1), whilst the reaction with the N-phenyl nitrone (1d) gives the expected oxazolidinone (3b).Cyano-t-butylketene reacts with diphenyl nitrone to give the indolones (10a) and (10b).The reaction of phenyl isocyanate with diphenyl nitrone, and the N-alkyl nitrones (1a) and (1d) gives the normal 1,3-dipolar cycloadducts without rearrangement.Ethoxycarbonyl-t-butylketene reacts with the N-phenyl nitrone (1d) to give an oxazolidinone , but reaction with the N-alkyl nitrones (1) gives only fluorenone azine.This ketene reacts with diphenyl nitrone to give the anil (15) and the dihydroindole (16).
