647861-84-5Relevant academic research and scientific papers
Metal-Stabilized Phenoxonium Cation
Vigalok, Arkadi,Rybtchinski, Boris,Gozin, Yael,Koblenz, Tehila S.,Ben-David, Yehoshoa,Rozenberg, Haim,Milstein, David
, p. 15692 - 15693 (2003)
An unprecedented metal-stabilized phenoxonium cation was prepared by a process involving dearomatization of a phenoxy complex. The unique η2 C=O-metal (iridium) coordination mode leaves the positive charge delocalized within the former aromatic ring. The X-ray structure and conversion into η2 C=O-coordinated metal-quinone complex are described. Copyright
