64806-62-8Relevant articles and documents
Synthesis of terminal perfluoroalkyl enol ethers and epoxy ethers
Begue, Jean-Pierre,Bonnet-Delpon, Daniele,Kornilov, Andrei
, p. 1057 - 1063 (1996)
A practical method for the multigram-scale preparation in good yields of terminal perfluoroalkyl enol ethers, using Wittig olefination of perfluoroalkyl ethers, is reported. The corresponding epoxy ethers are available via their m-CPBA epoxidation in good
A Simple Preparation of Alkyl Trifluoromethanesulfonates (Triflates) from Alkyl Trimethylsilyl Ethers
Aubert, Corinne,Begue, Jean-Pierre
, p. 759 - 760 (2007/10/02)
Several alkyl trifluoromethanesulfonates (triflates) 2 are prepared by reacting alkyl trimethylsilyl ethers 1 with trifluoromethanesulfonic anhydride.The triflates 2 can be used for further reactions without isolation, as illustrated in the preparation of the ether 3 and cumene (4).