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4119-41-9

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4119-41-9 Usage

Synthesis Reference(s)

Synthetic Communications, 18, p. 119, 1988 DOI: 10.1080/00397918808077334

Check Digit Verification of cas no

The CAS Registry Mumber 4119-41-9 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 4,1,1 and 9 respectively; the second part has 2 digits, 4 and 1 respectively.
Calculate Digit Verification of CAS Registry Number 4119-41:
(6*4)+(5*1)+(4*1)+(3*9)+(2*4)+(1*1)=69
69 % 10 = 9
So 4119-41-9 is a valid CAS Registry Number.
InChI:InChI=1/C9H11I/c10-8-4-7-9-5-2-1-3-6-9/h1-3,5-6H,4,7-8H2

4119-41-9 Well-known Company Product Price

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  • Alfa Aesar

  • (H53420)  3-Iodo-1-phenylpropane, 97%   

  • 4119-41-9

  • 1g

  • 362.0CNY

  • Detail
  • Alfa Aesar

  • (H53420)  3-Iodo-1-phenylpropane, 97%   

  • 4119-41-9

  • 5g

  • 1356.0CNY

  • Detail
  • Alfa Aesar

  • (H53420)  3-Iodo-1-phenylpropane, 97%   

  • 4119-41-9

  • 25g

  • 5422.0CNY

  • Detail

4119-41-9SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 12, 2017

Revision Date: Aug 12, 2017

1.Identification

1.1 GHS Product identifier

Product name 3-iodopropylbenzene

1.2 Other means of identification

Product number -
Other names Benzene, (3-iodopropyl)-

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:4119-41-9 SDS

4119-41-9Relevant articles and documents

Drury,Kaplan

, p. 2217,2218 (1973)

Iridium-Catalyzed Hydroiodination and Formal Hydroamination of Olefins with N-Iodo Reagents and Molecular Hydrogen: An Umpolung Strategy

Wen, Jialin,Yang, Huaxin,Zhang, Xumu,Zhang, Zhihan,Zhou, Yang

supporting information, p. 1842 - 1847 (2022/03/14)

We herein report a convenient method to convert olefins to organic iodides and amines using an Ir/ZhaoPhos catalyst, molecular hydrogen, and an electrophilic iodine(I) reagent. High yields and regioselectivities were obtained under mild conditions. In addition, basic workup with potassium carbonate leads to C-N products. Control experiments and DFT calculations tentatively excluded the pathway involving the in situ formation of HI. Instead, a catalytic cycle involving the hydrogenation of the haliranium ion intermediate was proposed.

Copper-Catalyzed Alkoxycarbonylation of Alkyl Iodides for the Synthesis of Aliphatic Esters: Hydrogen Makes the Difference

Geng, Hui-Qing,Wu, Xiao-Feng

supporting information, p. 8062 - 8066 (2021/10/25)

A copper-catalyzed alkoxycarbonylation transformation of unactivated alkyl iodides has been developed. Various alkyl iodides can be converted into the corresponding tert-butyl esters in good yields. NaOtBu acts as both a nucleophile and a base. Moreover, other types of aliphatic esters can also be obtained in moderated yields if extra alcohols are added. Both primary and secondary alkyl alcohols can react successfully.

Ligand Free Palladium-Catalyzed Synthesis of α-Trifluoromethylacrylic Acids and Related Acrylates by Three-Component Reaction

Bouillon, Jean-Philippe,Couve-Bonnaire, Samuel,Pannecoucke, Xavier,Xiao, Pan

supporting information, p. 949 - 954 (2020/01/28)

Aryl iodides and 2-(trifluoromethyl)acrylic acid reacted together in ligand-free Mizoroki-Heck reaction furnishing a quick and efficient access to highly valuable α-trifluoromethylacrylic acids. The useful transformation was independent with regard to the electronic nature of the aryl group substituent. A three-component one-pot version was also developed to give diverse substituted acrylates. The versatility of α-trifluoromethylacrylic acids was demonstrated by quick access to 3-CF3-coumarins as well as fluorinated analogues of therapeutic or cosmetic agents. Finally, we proposed a catalytic cycle based on the silver carboxylate salt, identified as a key intermediate in the reaction. (Figure presented.).

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