649571-93-7

Basic information

• Product Name: 5-[(3R,5S)-1-benzyl-3-hydroxy-2-oxo-5-pyrrolidinyl]-1,2:3,4-di-O-isopropylidene-α-D-galacto-pentopyranose
• Synonyms: 5-[(3R,5S)-1-benzyl-3-hydroxy-2-oxo-5-pyrrolidinyl]-1,2:3,4-di-O-isopropylidene-α-D-galacto-pentopyranose
• CAS NO: 649571-93-7
• Molecular Weight: 419.475
• Mol File: 649571-93-7.mol

Chemical Properties

• CAS DataBase Reference: 5-[(3R,5S)-1-benzyl-3-hydroxy-2-oxo-5-pyrrolidinyl]-1,2:3,4-di-O-isopropylidene-α-D-galacto-pentopyranose(CAS DataBase Reference)
• NIST Chemistry Reference: 5-[(3R,5S)-1-benzyl-3-hydroxy-2-oxo-5-pyrrolidinyl]-1,2:3,4-di-O-isopropylidene-α-D-galacto-pentopyranose(649571-93-7)
• EPA Substance Registry System: 5-[(3R,5S)-1-benzyl-3-hydroxy-2-oxo-5-pyrrolidinyl]-1,2:3,4-di-O-isopropylidene-α-D-galacto-pentopyranose(649571-93-7)

Safety Data

• Hazardous Substances Data: 649571-93-7(Hazardous Substances Data)

Upstream product

• 649571-87-9 4-[(3S,5R)-2-benzyl-5-(methoxycarbonyl)-3-isoxazolidinyl]-1,2:3,4-di-O-isopropylidene-α-D-galacto-pentopyranose 

Relevant articles and documents

1,3-Dipolar cycloaddition between N-benzyl-C-glycosyl nitrones and methyl acrylate en route to glycosyl pyrrolidines

1,3-Dipolar cycloaddition reactions between three N-benzyl-C-glycosyl nitrones and methyl acrylate afforded key intermediates for the synthesis of glycosyl pyrrolidines. The best result was obtained with a D-galactose derived nitrone which afforded only one isomer in quantitative yield. Absolute configurations were assigned by applying the Kakisawa's rule and X-ray diffraction methods.