6498-44-8Relevant articles and documents
Seyferth,Haas
, p. C33 (1972)
Applications of surfactant-modified clays to synthetic organic chemistry
Ghiaci,Sedaghat,Kalbasi,Abbaspur
, p. 5529 - 5534 (2007/10/03)
Two triphase catalysts (SLL) have been developed for organic phase-aqueous phase reactions catalyzed by suitable modified clay (solid phase). These triphase catalysts have been applied to nucleophilic displacement on activated (benzylic) as well as unactivated organic halides and provide a convenient and effective method of preparation of the corresponding products. Other useful transformations to, which these triphase catalysts have been successfully applied are the synthesis of 9,9-dichloro bicyclo[6.1.0]nonane, O-alkylation and C-alkylation of β-naphthol.
A new phase transfer reagent for the addition of dichlorocarbene to olefins under mild PTC conditions
Jayachandran, J. Paul,Wang, Maw-Ling
, p. 4101 - 4112 (2007/10/03)
A three-step synthetic route to a novel water soluble phase transfer reagent, Diquat (Dq-Br), viz., 2-benzilidine-N,N,N,N',N',N'- hexaethyl propane-1,3 diammonium dibromide and its utility in various dichlorocarbenations to olefins are described.
Ein stereochemischer Beweis fuer den Zweistufen-Mechanismus der Dihalogencarben-Addition
Dehmlow, Eckehard V.,Kramer, Roland
, p. 700 - 701 (2007/10/02)
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