65081-26-7Relevant academic research and scientific papers
Synthesis and catalytic reactivity in Friedel–Crafts acylations of monobridged bis(cyclopentadienyl)molybdenum(I) carbonyl complexes
Yan, Xin Long,Zhang, Ning,Hao, Zhi Qiang,Ma, Zhi Hong,Han, Zhan Gang,Zheng, Xue Zhong,Lin, Jin
, p. 75 - 79 (2018/04/11)
When the monobridged biscyclopentadienes (C5H5)R(C5H5) [R = C(CH3)2 (1), Si(CH3)2 (2), C(CH2)5 (3)] reacted with Mo(CO)6 in refluxing xylene, the corresponding complexes [(η5-C5H4)2R][Mo(CO)3]2 [R = C(CH3)2 (4), Si(CH3)2 (5), C(CH2)5 (6)] were obtained. These complexes were separated by chromatography and characterized by elemental analysis, IR, and 1H NMR spectroscopy. The molecular structures of 4 and 5 were determined by X-ray diffraction analysis. Friedel–Crafts acylation reactions of anisole derivatives with aromatic or aliphatic acyl chlorides catalyzed by complexes 4–6 showed that all of these monobridged bis(cyclopentadienyl)molybdenum carbonyl complexes have catalytic activity.
Tetralone esters as intermediates for the synthesis of podophyllotoxin derivatives via cyclopropanation of chalcones
Nanjundaswamy,Shashikanth,Anjanamurthy,Rai, K.M. Lokanatha
, p. 1179 - 1191 (2007/10/03)
Cyclopropyl ester (8a-f) were synthesized by the cyclopropanation of chalcones (7a-e) in dry benzene using powdered sodium in 80-85% yield. Preparation of tetralone ester (4a-e), an intermediate for the synthesis of podophyllotoxin derivatives by Lewis ac
