65094-99-7Relevant academic research and scientific papers
Enantioselective nitrene transfer to sulfides catalyzed by a chiral iron complex
Wang, Jun,Frings, Marcus,Bolm, Carsten
supporting information, p. 8661 - 8665 (2013/09/12)
Iron works: Enantioselective nitrene transfer to sulfide was accomplished by a chiral iron(III)/PyBOX catalyst (see scheme). Various sulfimides were thus obtained in high enantioselectivities and yields. Applications of this protocol to the syntheses of enantioenriched sulfoximines and an epoxide were also demonstrated. Copyright
Mechanistic Insight into Allylmetal-Thioacetal Reactions Employing 2-Acetoxy-2-phenylacetaldehyde Thioacetals
Sato, Tsuneo,Otera, Junzo,Nozaki, Hitosi
, p. 6116 - 6121 (2007/10/02)
The mechanism of allyl-metal-thioacetal reactions has been investigated by using 2-acetoxy-2-phenylacetaldehyde thioacetals in the presence of trimethylsilyl triflate.The results unambiguously revealed the occurence of both SN1- and SN/su
