651322-83-7Relevant academic research and scientific papers
Studies Directed toward the Total Synthesis of Lactonamycin: Control of the Sense of Cycloaddition of a Quinone through Directed Intramolecular Catalysis
Cox, Christopher D.,Siu, Tony,Danishefsky, Samuel J.
, p. 5625 - 5629 (2007/10/03)
The rapid assembly of the ABCD tetracyclic ring system of lactonamycin involved the strong-base-induced regioselective Diels-Alder reaction of 1 and 2 to form advanced precursor 3. Regiochemical control results from the suitably positioned hydroxy group,
