651735-90-9

Upstream product

• 128657-58-9 methyl 2-amino-4,6-O-benzylidene-2-deoxy-α-D-glucopyranoside 
• 34270-90-1 2,2'-diiodoethyl ether 
• 651736-08-2 methyl 4,6-O-benzylidene-α-D-arabino-hexopyranoside-2-ulose Z-oxime 

Downstream Products

• 848477-39-4 methyl 4,6-O-benzylidene-2-deoxy-2-(4-morpholinyl)-α-D-ribo-hexopyranoside-3-ulose 

Relevant academic research and scientific papers

Enantioselective arylations catalyzed by carbohydrate-based chiral amino alcohols

The application of carbohydrate-derived amino alcohols in the asymmetric arylation of aldehydes by using arylboronic acids as the source of transferable aryl groups is described. The best ligand is derived from the readily available sugar D-xylose and it mediates the addition of a range of arylboronic acids to various aromatic aldehydes in excellent yields and high enantiomeric excesses.

Carbohydrate-derived aminoalcohol ligands for asymmetric Reformatsky reactions

Members of a family of functionally and stereochemically diverse d-glucosamine-derived tertiary aminoalcohol ligands have been used to promote the asymmetric Reformatsky reaction. The β-hydroxyester product tert-butyl 3-phenyl-3-hydroxy-propanoate was obt

Precise structure activity relationships in asymmetric catalysis using carbohydrate scaffolds to allow ready fine tuning: dialkylzinc-aldehyde additions.

The ready construction of 24 stereochemically and functionally diverse carbohydrate ligand structures from a core D-glucosamine scaffold has allowed the evaluation of broad ranging structure activity relationships in ligand accelerated zincate additions t