651736-08-2Relevant articles and documents
Precise structure activity relationships in asymmetric catalysis using carbohydrate scaffolds to allow ready fine tuning: dialkylzinc-aldehyde additions.
Emmerson, Daniel P G,Villard, Renaud,Mugnaini, Claudia,Batsanov, Andrei,Howard, Judith A K,Hems, William P,Tooze, Robert P,Davis, Benjamin G
, p. 3826 - 3838 (2003)
The ready construction of 24 stereochemically and functionally diverse carbohydrate ligand structures from a core D-glucosamine scaffold has allowed the evaluation of broad ranging structure activity relationships in ligand accelerated zincate additions t
Carbohydrate-derived aminoalcohol ligands for asymmetric Reformatsky reactions
Emmerson, Daniel P.G.,Hems, William P.,Davis, Benjamin G.
, p. 213 - 221 (2007/10/03)
Members of a family of functionally and stereochemically diverse d-glucosamine-derived tertiary aminoalcohol ligands have been used to promote the asymmetric Reformatsky reaction. The β-hydroxyester product tert-butyl 3-phenyl-3-hydroxy-propanoate was obt