65182-59-4Relevant articles and documents
New naphthyridine-based bipolar host materials for thermally activated delayed fluorescent organic light-emitting diodes
Yeh, Tzu-Chin,Lee, Jhen-De,Chen, Lu-Yu,Chatterjee, Tanmay,Hung, Wen-Yi,Wong, Ken-Tsung
, p. 55 - 62 (2019/04/17)
A series of bipolar host materials, namely, o-, m-, p-NPCz and o-, m-, p-NPDa, composing of electron-transporting naphthyridine (NP) and phenylene bridge with ortho-, meta-, and para-substituted hole-transporting carbazole (Cz)/diphenylamine (Da) were synthesized and characterized. By adjusting the linkage topology, the physical properties are subtly tuned. The characteristics of devices employing these new bipolar hosts with green thermally activated delayed fluorescence (TADF) emitter 1,2,3,5-tetrakis(carbazol-9-yl)-4,6-dicyanobenzene (4CzIPN) employed as emitter were investigated under the same device structure. Among these hosts, carbazole-based NPCz can perform efficient energy transfer from the host to the dopant and better exciton confinement in the emitting layer due to higher triplet energy and deeper HOMO/LUMO level than those of diphenylamine-based NPDa. The device with o-NPCz as bipolar host exhibits the best device performance with external quantum efficiency of 18.4% and low efficiency roll-off. However, o-, m-, p-NPDa with lower ET and shallower HOMO levels than 4CzIPN exhibit inferior host to dopant energy transfer. Instead, the exciplex formation between host and 4CzIPN, which was verified by TRPL, led the resulting EL spectra of the NPDa-based devices broad with yellow to orange emissions.
Transition metal-free α-methylation of 1,8-naphthyridine derivatives using DMSO as methylation reagent
Jiang, Shaohua,Yang, Zhihai,Guo, Ziyin,Li, Yibiao,Chen, Lu,Zhu, Zhongzhi,Chen, Xiuwen
, p. 7416 - 7424 (2019/08/15)
A practical approach to the direct α-methylation of 1,8-naphthyridines under mild reaction conditions has been developed using simple and readily available DMSO as a convenient and environmentally friendly carbon source. This method is transition metal-free and highly chemoselective, shows good functional group tolerance, and uses DMSO as a methyl source, providing efficient and rapid access to an important compound class, 2-methyl-1,8-naphthyridines.
Ruthenium-Catalyzed Enantioselective Hydrogenation of 1,8-Naphthyridine Derivatives
Ma, Wenpeng,Chen, Fei,Liu, Youran,He, Yan-Mei,Fan, Qing-Hua
, p. 2730 - 2733 (2016/06/15)
The first asymmetric hydrogenation of 2,7-disubstituted 1,8-naphthyridines catalyzed by chiral cationic ruthenium diamine complexes has been developed. A wide range of 1,8-naphthyridine derivatives were effectively hydrogenated to give 1,2,3,4-tetrahydro-1,8-naphthyridines with up to 99% ee and full conversions. The method provides a practical and facile approach to the preparation of valuable chiral heterocyclic building blocks and useful motifs for a new kind of P,N-ligand.