65190-43-4

Basic information

• Product Name: .beta.-D-Glucopyranose, 1,6-anhydro-2-deoxy-2-methyl-4-O-(phenylmethyl)-
• Synonyms: .beta.-D-Glucopyranose, 1,6-anhydro-2-deoxy-2-methyl-4-O-(phenylmethyl)-
• CAS NO: 65190-43-4
• Molecular Formula: C₁₄H₁₈O₄
• Molecular Weight: 250.29
• Mol File: 65190-43-4.mol
• Article Data: 2

Chemical Properties

• Appearance: /
• CAS DataBase Reference: .beta.-D-Glucopyranose, 1,6-anhydro-2-deoxy-2-methyl-4-O-(phenylmethyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: .beta.-D-Glucopyranose, 1,6-anhydro-2-deoxy-2-methyl-4-O-(phenylmethyl)-(65190-43-4)
• EPA Substance Registry System: .beta.-D-Glucopyranose, 1,6-anhydro-2-deoxy-2-methyl-4-O-(phenylmethyl)-(65190-43-4)

Safety Data

• Hazardous Substances Data: 65190-43-4(Hazardous Substances Data)

Upstream product

• 33208-47-8 4-O-benzyl-1,6:2,3-dianhydro-β-D-mannopyranose 
• 917-54-4 methyllithium 
• 2999-74-8 dimethylmagnesium 

Downstream Products

• 365441-25-4 (2R,3R,4R,5S,6R)-4,5-Bis-benzyloxy-6-hydroxymethyl-3-methyl-tetrahydro-pyran-2-carboxylic acid methyl ester 
• 365441-21-0 (2R,3R,4R,5S,6R)-4,5-Bis-benzyloxy-6-(tert-butyl-dimethyl-silanyloxymethyl)-3-methyl-tetrahydro-pyran-2-carbaldehyde 
• 365441-13-0 (2R,3R,4R,5S,6R)-4,5-Bis-benzyloxy-6-(tert-butyl-dimethyl-silanyloxymethyl)-3-methyl-tetrahydro-pyran-2-carboxylic acid methyl ester 
• 365441-09-4 (2R,3R,4R,5S,6R)-4,5-Bis-benzyloxy-6-(tert-butyl-dimethyl-silanyloxymethyl)-3-methyl-tetrahydro-pyran-2-carboxylic acid methoxy-methyl-amide 
• 627537-41-1 (1R,4S,5R,6R)-1-((2R,3R,4R,5S,6R)-4,5-Bis-benzyloxy-6-hydroxymethyl-3-methyl-tetrahydro-pyran-2-yl)-6-(4-methoxy-benzyloxy)-5-methyl-2-methylene-10-trityloxy-decane-1,4-diol 
• 365441-29-8 2,2-dimethyl-propionic acid 3,4-bis-benzyloxy-6-{1-(tert-butyl-dimethyl-silanyloxy)-2-[2-(tert-butyl-dimethyl-silanyloxy)-8-hydroxy-4-(4-methoxy-benzyloxy)-3-methyl-octyl]-allyl}-5-methyl-tetrahydro-pyran-2-ylmethyl ester 
• 627537-33-1 2,2-Dimethyl-propionic acid (2R,3S,4R,5R,6R)-3,4-bis-benzyloxy-6-[(1R,4S,5R,6R)-1,4-dihydroxy-6-(4-methoxy-benzyloxy)-5-methyl-2-methylene-10-trityloxy-decyl]-5-methyl-tetrahydro-pyran-2-ylmethyl ester 
• 365441-18-5 (4S,5S,6R)-1-[(2R,3R,4R,5S,6R)-4,5-Bis-benzyloxy-6-(tert-butyl-dimethyl-silanyloxymethyl)-3-methyl-tetrahydro-pyran-2-yl]-4-(tert-butyl-dimethyl-silanyloxy)-6-(4-methoxy-benzyloxy)-5-methyl-2-methylene-10-trityloxy-decan-1-one 
• 365441-19-6 (1R,4S,5S,6R)-1-[(2R,3R,4R,5S,6R)-4,5-Bis-benzyloxy-6-(tert-butyl-dimethyl-silanyloxymethyl)-3-methyl-tetrahydro-pyran-2-yl]-4-(tert-butyl-dimethyl-silanyloxy)-6-(4-methoxy-benzyloxy)-5-methyl-2-methylene-10-trityloxy-decan-1-ol 
• 365441-30-1 2,2-dimethyl-propionic acid 3,4-bis-benzyloxy-6-{1-(tert-butyl-dimethyl-silanyloxy)-2-[2-(tert-butyl-dimethyl-silanyloxy)-8-(tert-butyl-diphenyl-silanyloxy)-4-(4-methoxy-benzyloxy)-3-methyl-octyl]-allyl}-5-methyl-tetrahydro-pyran-2-ylmethyl ester 
• 365441-22-1 2,2-dimethyl-propionic acid 3,4-bis-benzyloxy-6-{1-(tert-butyl-dimethyl-silanyloxy)-2-[2-(tert-butyl-dimethyl-silanyloxy)-4-(4-methoxy-benzyloxy)-3-methyl-8-trityloxy-octyl]-allyl}-5-methyl-tetrahydro-pyran-2-ylmethyl ester 
• 1148029-12-2 (2R,3S,4R,5R)-3-(benzyloxy)-5-(1,3-dithian-2-yl)hexane-1,2,4-triol 
• 65190-44-5 4-O-benzyl-2-methyl-3-acetoxy-1,6-anhydro-β-D-glucopyranose 
• 112339-02-3 1,6-Anhydro-4-O-benzyl-2,3-dideoxy-2-C-methyl-β-D-ribo-hexopyranose 

Relevant articles and documents

Open chain chiral macrolide building blocks by opening of deoxygenated 1,6-anhydrosugars with 1,3-propanedithiol

Chiral building blocks for macrolides and related natural products are obtained from 1,6-anhydrosugars by conversion of the bicyclic acetals 2 or 12 into the open chain chiral 1,3-dithianes 6 and 13. Branched precursors can be obtained by opening of the C