652152-26-6Relevant academic research and scientific papers
Pyrimidin-/thiazol-/thiazolin-ylidenamidothiophosphoric dichlorides
Kabra, Vijaya,Gupta, Neelima,Jain, Sama,Saxena, Varsha
, p. 498 - 502 (2003)
Nine new amidodichlorothiophosphorus(V) derivatives incorporating pyrimidine, thiazole, and thiazoline rings were obtained by sulfurization of the corresponding aminodichlorophosphines generated in situ from the reaction of the respective N-alkyl-2-aminoc
One-pot synthesis and fungicidal activity of pyrimidinylidenamido- and thiazolinylidenamidomonothiophosphoric esters
Gupta, Neelima,Kabra, Vijaya,Saxena, Varsha,Jain, Sama,Bhatnager, Kalpana
, p. 851 - 861 (2007/10/03)
A novel one-pot synthesis of four new classes of amidothiophosphoric esters and trisamidothiophosphoric esters is developed. (1-Alkyl-2-pyrimidinylidenamido)bis(diethylamido)thiophosphates, (1-alkyl-2-pyrimidinylidenamido)bis(O-214-methylphenyl)thiophosphates, (3-alkyl-2-thiazolinylidenamido)bis (diethylamido)thiophosphate and (3-alkyl-2-thiazolinylidenamido)bis(O-214-methylphenyl)thiophosphates are obtained from the nucleophilic substitution and oxidation of N-alkyl-2-cycloiminylidenaminodichlorophosphines generated in situ from the reaction of the corresponding N-alkyl-2-amino-cycloiminium halide with phosphorus trichloride and triethylamine. The synthesized thiophosphoric esters have been investigated for fungicidal properties.
