652153-16-7

Basic information

• Product Name: (4aR,6R,8aS)-3,4,4a,5,6,7,8,8a-octahydro-8a-methyl-6-(phenylmethoxy)naphthalen-1-carboxylic acid methyl ester
• Synonyms: (4aR,6R,8aS)-3,4,4a,5,6,7,8,8a-octahydro-8a-methyl-6-(phenylmethoxy)naphthalen-1-carboxylic acid methyl ester
• CAS NO: 652153-16-7
• Molecular Weight: 314.425
• Mol File: 652153-16-7.mol

Chemical Properties

• CAS DataBase Reference: (4aR,6R,8aS)-3,4,4a,5,6,7,8,8a-octahydro-8a-methyl-6-(phenylmethoxy)naphthalen-1-carboxylic acid methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: (4aR,6R,8aS)-3,4,4a,5,6,7,8,8a-octahydro-8a-methyl-6-(phenylmethoxy)naphthalen-1-carboxylic acid methyl ester(652153-16-7)
• EPA Substance Registry System: (4aR,6R,8aS)-3,4,4a,5,6,7,8,8a-octahydro-8a-methyl-6-(phenylmethoxy)naphthalen-1-carboxylic acid methyl ester(652153-16-7)

Safety Data

• Hazardous Substances Data: 652153-16-7(Hazardous Substances Data)

Upstream product

• 67-56-1 methanol 
• 201230-82-2 carbon monoxide 
• 652153-15-6 (4aR,6R,8aS)-3,4,4a,5,6,7,8,8a-octahydro-8a-methyl-6-(phenylmethoxy)naphthalen-1-ol trifluoronethanesulfonate 

Downstream Products

• 652153-29-2 Thiocarbonic acid O-((4aR,4bS,6aR,8R,10aR,10bR,12aR)-8-benzyloxy-2-methoxy-1,1,10a-trimethyl-4,11-dioxo-1,4b,5,6,6a,7,8,9,10,10a,10b,11,12,12a-tetradecahydro-4H-chrysen-4a-ylmethyl) ester O-phenyl ester 
• 652153-21-4 (4aR,4bS,6aR,8R,10aR,10bR,12aR)-4b,5,6,6a,7,8,9,10,10a,10b,12,12a-dodecahydro-4a-(hydroxymethyl)-2-methoxy-1,1,10a-trimethyl-8-(phenylmethoxy)chrysene-4,11(1H,4aH)-dione 
• 652153-11-2 (4aR,4bS,6aR,8R,10aR,10bR,12aR)-1,4,4a,4b,5,6,7,8,9,10,10a,10b,11,12,12a-hexadecahydro-2-methoxy-1,1,10a-trimethyl-4,11-dioxo-8-(phenylmethoxy)chrysene-4a-carboxaldehyde 
• 652153-22-5 (4aR,4bS,6aR,8R,10aR,10bR,12aR)-4b,5,6,6a,7,8,9,10,10a,10b,12,12a-dodecahydro-2-methoxy-1,1,4a,10a-tetramethyl-8-(phenylmethoxy)chrysene-4,11(1H,4aH)-dione 
• 652153-13-4 (4aR,6R,8aS)-3,4,4a,5,6,7,8,8a-octahydro-8a-methoxy-β-oxo-6-(phenylmethoxy)naphthalene-1-propanoic acid prop-2-enyl ester 
• 652153-18-9 (4aR,6R,8aS)-3,4,4a,5,6,7,8,8a-octahydro-8a-methyl-β-oxo-6-(phenylmethoxy)naphthalene-1-propanoic acid 1,1-dimethylethyl ester 
• 652153-24-7 3-((4aR,6R,8aR)-6-Benzyloxy-8a-methyl-3,4,4a,5,6,7,8,8a-octahydro-naphthalen-1-yl)-3-hydroxy-propionic acid tert-butyl ester 
• 652153-17-8 (4aR,6R,8aS)-3,4,4a,5,6,7,8,8a-octahydro-8a-methyl-6-(phenylmethoxy)naphthalene-1-carboxaldehyde 
• 652153-23-6 ((4aR,6R,8aR)-6-Benzyloxy-8a-methyl-3,4,4a,5,6,7,8,8a-octahydro-naphthalen-1-yl)-methanol 

Relevant articles and documents

Enantioselective Synthesis of a Polyfunctionalized Tetracycle Related to Pentacyclic Triterpenes by Using an Anionic Cycloaddition Reaction

Herein we report a convergent enantioselective synthesis of a polyfunctionalized ABCD tetracycle by using an anionic cycloaddition reaction between a chiral bicyclic CD Nazarov intermediate (see 6), derived from the (-)-Weiland-Mischer ketone, and an achi