652154-92-2Relevant academic research and scientific papers
Enantioselective cyclization/hydrosilylation of 1,6-enynes catalyzed by a cationic rhodium bis(phosphine) complex
Chakrapani, Harinath,Liu, Cong,Widenhoefer, Ross A.
, p. 157 - 159 (2003)
(Matrix presented) Reaction of 4,4-dicarbomethoxy-1-octene-6-yne (1) with triethylsilane and a catalytic 1:1 mixture of [Rh(COD)2]+ SbF6- and (R)-BIPHEMP (5 mol %) at 70°C for 90 min gave (Z)-1,1-dicarbomethoxy-
Selective Oxidation of Zirconocyclopentenes via Organoboranes
Gorman, Jeffrey S. T.,Iacono, Scott T.,Pagenkopf, Brian L.
, p. 67 - 70 (2007/10/03)
(Equation presented) A new, convenient, one-pot protocol is described for oxidation of zirconocyclopent-2-enes selectively at the sp3 carbon by efficient transfer to electrophilic (cHeX)2BCl followed by oxidation with Hsu
