65236-05-7Relevant academic research and scientific papers
Synthesis of carbamothioate derivatives via a copper catalyzed thiocarboxamidation of aryl iodides
Khalaj, Mehdi
, p. 945 - 952 (2020/05/26)
Abstract: A catalytic route to carbamothioate derivatives through a reaction involving isocyanides, elemental sulfur, and aryl iodides has been developed. The reaction scope has been examined using a range of isocyanides and aryl iodides. The reactions involve two consecutive C–S bond formations. Control experiment revealed that the reaction proceeds through an iminium species. Graphic abstract: [Figure not available: see fulltext.].
KI-catalyzed synthesis of S-Thiocarbamates by cross-coupling of cyclohexyl isocyanide with sulfonyl chlorides
Lin, Liangwei,Fang, Zhengjun,Li, Yajun,Wu, Feng,Au, Chaktong,Luo, Sai
, p. 347 - 351 (2019/08/12)
A simple and efficient process for direct generation of various S-thiocarbamates is developed by cross-coupling of readily available sulfonyl chlorides with cyclohexyl isocyanide. The yields are excellent and the structures of the generated S-thiocarbamat
Molecular iodine-mediated synthesis of thiocarbamates from thiols, isocyanides and water under metal-free conditions
Bao, Wen-Hu,Wu, Chao,Wang, Jing-Ting,Xia, Wen,Chen, Ping,Tang, Zilong,Xu, Xinhua,He, Wei-Min
supporting information, p. 7025 - 7029 (2018/10/02)
A simple and practical molecular iodine-mediated method for the efficient construction of thiocarbamates from isocyanides, thiols and water under metal-free and mild conditions has been developed. A variety of thiocarbamates were easily synthesized through this methodology, which has the advantages of simple operation, eco-friendly conditions, good functional group tolerance, and readily accessible raw materials.
Iodine-catalyzed cross-coupling of isocyanides and thiols for the synthesis of: S -thiocarbamates
Pathare, Ramdas S.,Patil, Vikas,Kaur, Harpreet,Maurya, Antim K.,Agnihotri, Vijai K.,Khan, Shahnawaz,Devunuri, Nagaraju,Sharon, Ashoke,Sawant, Devesh M.
supporting information, p. 6885 - 6888 (2018/10/02)
A novel and efficient metal free, redox-neutral method for the synthesis of secondary thiocarbamates by cross-coupling of readily available thiophenol and isocyanides has been developed. The present methodology exhibits a broad substrate scope with good to excellent yields without an additive/extra oxidant under mild reaction conditions catalyzed by inexpensive iodine as the catalyst.
Method of controlling pea aphids
-
, (2008/06/13)
Novel S-aryl N-cycloalkylthiolcarbamates, such as S-4-methoxy-phenyl N-cyclohexylthiolcarbamate, which are useful for controlling pea aphids, and the method of controlling pea aphids with the compounds are disclosed.
