65271-13-8Relevant academic research and scientific papers
A mild method for the synthesis of β-enaminones and β-enamino esters using KH2P04 as catalyst
Xu, Feng,Lv, Hong-Xia,Wang, Jin-Ping,Tian, You-Ping,Wang, Jian-Jun
experimental part, p. 707 - 710 (2009/10/02)
β-Enaminones and β-enamino esters have been produced by the direct condensation of amines with β-diketones and β-ketoesters using KH2P04 as catalyst under mild, solvent-free conditions.
Enamination of β-dicarbonyl compounds with amines
Khodaei,Khosropour,Cardel
scheme or table, p. 217 - 221 (2009/04/06)
Enamination of a wide variety of primary amines was successfully described with excellent chemoselectivity in the presence of catalytic amounts of β-cyclodextrin in water under mild conditions. Aliphatic amines also reacted efficiently to produce the corresponding enaminones.
Highly efficient microwave-accelerated preparation of β-ketoimines
Lee, Dong Hwan,Park, Sang-Eon,Cho, Kyuho,Kim, Younsoo,Athar, Taimur,Lee, Ik-Mo
, p. 8281 - 8284 (2008/03/30)
We present here a new and efficient methodology for the β-ketoimine ligand with microwave heating system. The new method showed faster reaction rates, higher yields, and selectivities of the desired compounds in the absence of solvents.
A novel enamination of β-dicarbonyl compounds catalyzed by Bi(TFA)3 immobilized on molten TBAB
Khodaei, Mohammad M.,Khosropour, Ahmad R.,Kookhazadeh, Mehdi
, p. 209 - 212 (2007/10/03)
Enamination of a wide variety of primary amines was successfully carried out in the presence of catalytic amounts of bismuth(III) trifluoroacetate immobilized on molten tetrabutylammonium bromide as "green" media under mild conditions. This new system of the catalyst is recyclable and reusable. Generally, the results of the reaction in tetrabutylammonium bromide is better than the previously obtained results in water because of their yields and reaction times.
Cerium(III) chloride heptahydrate (CeCl3·7H2O) as an efficient enamination catalyst in aqueous media
Khodaei,Khosropour,Kookhazadeh
, p. 1445 - 1448 (2007/10/03)
Cerium(III) chloride heptahydrate CeCl3·H2O catalyzes enamination of β-dicarbonyl compounds with primary amines in aqueous medium at room temperature to afford the corresponding β-enamino ketones with high chemoselectivity.
A mild, efficient and environmentally friendly method for the regio- and chemoselective synthesis of enaminones using Bi(TFA)3 as a reusable catalyst in aqueous media
Khosropour, Ahmad R.,Khodaei, Mohammad M.,Kookhazadeh, Mehdi
, p. 1725 - 1728 (2007/10/03)
Bismuth(III) trifluoroacetate has been found to be an extremely efficient catalyst for the preparation of β-enaminones in water. In addition, by employing this catalyst, high regio- and chemoselective enamination of carbonyl compounds was achieved.
Enamination of β-dicarbonyl compounds catalyzed by CeCl 3·7H2O at ambient conditions: Ionic liquid and solvent-free media
Khodaei, Mohammad Mehdi,Khosropour, Ahmad Reza,Kookhazadeh, Mehdi
, p. 1980 - 1984 (2007/10/03)
Enamination of a wide various primary amines was successfully carried out in the presence of catalytic amounts of cerium chloride heptahydrate in ionic liquid and solvent-free conditions as 'green' media under mild reaction conditions.
An easy synthesis of enaminones in water as solvent
Stefani,Costa,De Silva
, p. 1526 - 1528 (2007/10/03)
Enaminones were prepared from β-ketoesters or 1,3-diketones and primary amines in water as solvent.
