65275-36-7

Basic information

• Product Name: Benzene, [(2-phenylethyl)seleno]-
• CAS NO: 65275-36-7
• Molecular Formula: C14H14Se
• Molecular Weight: 261.225
• Mol File: 65275-36-7.mol
• Article Data: 12

Chemical Properties

• CAS DataBase Reference: Benzene, [(2-phenylethyl)seleno]-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, [(2-phenylethyl)seleno]-(65275-36-7)
• EPA Substance Registry System: Benzene, [(2-phenylethyl)seleno]-(65275-36-7)

Safety Data

• Hazardous Substances Data: 65275-36-7(Hazardous Substances Data)

Upstream product

• 1482-82-2 dibenzyl diselenide 
• 98-80-6 phenylboronic acid 
• 17376-04-4 2-phenethyl iodide 
• 1666-13-3 diphenyl diselenide 
• 2179-79-5 phenyl selenocyanate 
• 60-12-8 2-phenylethanol 
• 224627-22-9 1,2-diphenyl-1-phenylseleno-2-ethanone 
• 103-63-9 1-phenyl-2-bromoethane 
• 114050-31-6 3-Phenyl-propionic acid 2-thioxo-2H-pyridin-1-yl ester 
• 17697-12-0 benzeneseleninic anhydride 
• 134480-11-8 N-Cyclohexylidene-N'-phenethyl-hydrazine 
• 4545-20-4 benzophenone tosylhydrazone 

Downstream Products

• 65275-53-8 β-Phenethyl-phenyl-selenoxid 
• 1386397-44-9 C₁₆H₁₆O₂Se 
• 343324-15-2 1-(2-Phenylaethyliden)-3,5,5-trimethyl-2-cyclohexen 
• 79482-86-3 1-Phenyl-2,4-hexadiene 
• 3558-60-9 1-methoxy-2-phenylethane 
• 17791-55-8 1,5-diphenylpenta-1,4-dien-3-ol 

Relevant articles and documents

A highly efficient heterogeneous ruthenium(III)-catalyzed reaction of diaryl diselenides with alkyl halides leading to unsymmetrical diorganyl selenides

A highly efficient heterogeneous ruthenium(III)-catalyzed reaction of diaryl diselenides with alkyl halides was achieved in DMF at 100?°C in the presence of 2?mol% of an MCM-41-immobilized bidentate nitrogen ruthenium(III) complex [MCM-41-2N-RuCl3] and zinc, yielding a variety of unsymmetrical diorganyl selenides in good to excellent yields. This new heterogeneous ruthenium catalyst can easily be prepared via a simple two-step procedure from commercially readily available and inexpensive reagents, and recovered by filtration of the reaction solution and recycled for at least eight times without a significant loss of activity.

Convenient synthesis of unsymmetrical organochalcogenides using organoboronic acids with dichalcogenides via cleavage of the S-S, Se-Se, or Te-Te bond by a copper catalyst

(Chemical Equation Presented) This article describes the methodology for a copper-catalyzed preparation of numerous monochalcogenides from dichalcogenides with organoboronic acids. Unsymmetrical diorgano-monosulfides, selenides, and tellurides can be synthesized by the coupling of dichalcogenides with aryl- or alkylboronic acids using a copper catalyst in air. The present reaction can take advantage of both organochalcogenide groups on dichalcogenide.

Indium(I) iodide-mediated cleavage of diphenyl diselenide. An efficient one-pot procedure for the synthesis of unsymmetrical diorganyl selenides

(Matrix presented) A simple and efficient procedure has been developed for the synthesis of unsymmetrical diorganyl selenides through a one-pot indium(I) iodide-mediated reaction of alkyl halide and diphenyl diselenide in methylene chloride at room temperature.