652986-45-3Relevant academic research and scientific papers
Synthesis of C3-C21 Segment of Aflastatin A Using Remote Asymmetric Induction Reactions
Murakoshi, Sawato,Hosokawa, Seijiro
supporting information, p. 758 - 761 (2019/01/21)
The C3-C21 segment of aflastatin A has been synthesized by converging three segments including the C3-C8 segment, the C9-C15 segment, and the C16-C21 segment. Each segment has been synthesized from a vinylketene silyl N,O-acetal possessing a chiral auxili
Crotylsilane reagents in the synthesis of complex polyketide natural products: Total synthesis of (+)-discodermolide
Arefolov, Alexander,Panek, James S.
, p. 5596 - 5603 (2007/10/03)
An efficient, highly convergent stereocontrolled synthesis of (+)-discodermolide has been achieved with 2.1% overall yield (27 steps longest linear sequence). The absolute stereochemistry of the C1-C6 (12), C7-C14 (13), and C15-C24 (11) subunits was intro
