65300-04-1

Upstream product

• 124700-90-9 bis(triphenylphosphine)iminium acetylacetonate 
• 219638-47-8 gold(III)(pentafluorophenyl)3(P(phenyl)2H) complex 
• 58452-28-1 tetrakis(acetonitrile)copper(I) trifluoromethanesulfonate 

Downstream Products

• 86086-81-9 bis-(triphenylphosphine)iminium-bis-methoxophthalocyaninatoferrate(III) 
• 86086-83-1 bis-(triphenylphosphine)iminium-bis-t-butoxophthalocyaninatoferrate(III) 
• 86086-87-5 bis-(triphenylphosphine)iminium-bis-i-propoxophthalocyaninatoferrate(III) 
• 86086-85-3 bis-(triphenylphosphine)iminium-bis-ethoxophthalocyaninatoferrate(III) 
• 88152-28-7 [N(PPh₃)2][Tl(2,4,6-C₆F₃H₂)3(CN)] 
• 88152-30-1 [N(P(C₆H₅)3)2]⁽¹⁺⁾*[Tl(C₆F₅)3(CN)]^(1-)=[N(P(C₆H₅)3)2][Tl(C₆F₅)3(CN)] 
• 102588-66-9 bis(triphenylphosphine)nitrogen diphenoxo(phthalocyaninato)ferrate(III) 

Relevant academic research and scientific papers

[Au(C6F5)3(PPh2H)]: A precursor for the synthesis of gold(III) phosphide complexes

The covalent radius of Au(I) is about 0.07 A smaller than that of Ag(I). This was determined from the crystal structures of the isostructural complexes [N(PPh3][{Au(C6F5)3-(μ-PPh2)}2M] (M = Au (structure shown in the picture), Ag). These mixed Au(III)-M phosphides were synthesized from [Au(C6F5)3-(PPh2H)], the first gold complex to contain a secondary phosphane.