219638-47-8Relevant academic research and scientific papers
[Au(C6F5)3(PPh2H)]: A precursor for the synthesis of gold(III) phosphide complexes
Blanco, M. Carmen,Fernandez, Eduardo J.,Jones, Peter G.,Laguna, Antonio,Lopez-de-Luzuriaga, Jose M.,Olmos, M. Elena
, p. 3042 - 3043 (1998)
The covalent radius of Au(I) is about 0.07 A smaller than that of Ag(I). This was determined from the crystal structures of the isostructural complexes [N(PPh3][{Au(C6F5)3-(μ-PPh2)}2M] (M = Au (structure shown in the picture), Ag). These mixed Au(III)-M phosphides were synthesized from [Au(C6F5)3-(PPh2H)], the first gold complex to contain a secondary phosphane.
