65343-56-8Relevant academic research and scientific papers
Synthesis of N-acyl-1,3-oxathiol-2-imines
Kulka, Marshall
, p. 1557 - 1559 (2007/10/02)
A facile synthesis of N-acyl-1,3-oxathiol-2-imines, 7, is reported.It comprises the reaction of O-alkyl acylcarbamothioates, 4, with 2-chloroketones in the presence of alcoholic sodium alkoxide.The resulting O-alkyl-S-substituted-N-acylcarbonimidothiates, 6, undergo cyclization with elimination of alcohol, spontaneously, or upon heating in boiling toluene to form 7.
