65367-63-7Relevant academic research and scientific papers
Synthesis of isomeric polyacetylenes based on natural hydroxy matricaria esters
Garrais, Solange,Turkington, Jennifer,Goldring, William P.D.
experimental part, p. 8418 - 8427 (2009/12/26)
The construction of a library of natural and related polyacetylenes using a convergent synthetic strategy based on a palladium mediated cross-coupling reaction is described. The systematic synthetic study led to all possible alkene isomers of the hydroxy matricaria esters 29-32, and the corresponding tiglates 1-4. The synthesis of many of these compounds is described for the first time.
In situ alcohol oxidation-Wittig reactions
Wei, Xudong,Taylor, Richard J. K.
, p. 3815 - 3818 (2007/10/03)
Allytic, propargylic and benzylic alcohols can be oxidised with activated manganese dioxide in the presence of stabilised Wittig reagents to generate α, β-unsaturated esters directly. This simple procedure, which can also be utilised with diols to give do
