65398-77-8Relevant academic research and scientific papers
Cu-catalyzed [2 + 2 + 1] cascade annulation of vinyl iodonium salts with elemental sulfur/selenium for the modular synthesis of thiophenes and selenophenes
Chen, Chao,Wang, Fei,Wu, Chao,Wu, Yaxing
supporting information, p. 945 - 949 (2022/02/01)
A [2 + 2 + 1] annulation protocol has been established for the modular synthesis of 2,4-disubstituted thiophenes/selenophenes, with excellent regioselectivity. The reactions have been catalyzed by copper salt with elemental sulfur and selenium serving as
Efficient Thiophene Synthesis Mediated by 1,3-Bis(carboxymethyl)imidazolium Chloride: C-C and C-S Bond Formation
Gisbert, Patricia,Pastor, Isidro M.
, p. 4319 - 4325 (2020/07/16)
Thiophene derivatives have been prepared by means of a functionalized imidazolium salt [1,3-bis(carboxymethyl)imidazolium chloride] acting as a catalyst. The heterogeneous catalyst has allowed to carry out the reactions with no solvent or inert atmosphere
Transition-Metal-Free Sulfuration/Annulation of Alkenes: Economical Access to Thiophenes Enabled by the Cleavage of Multiple C-H Bonds
Chen, Liang,Min, Hao,Zeng, Weilan,Zhu, Xiaoming,Liang, Yun,Deng, Guobo,Yang, Yuan
, p. 7392 - 7395 (2019/01/03)
A novel, atom economical, and transition-metal-free strategy for the synthesis of thiophenes from substituted buta-1-enes with potassium sulfide has been presented. The reaction achieves double C-S bond formations via cleavage of multiple C-H bonds and provides an efficient approach to access various functionalized thiophenes. Moreover, the strategy can also be used for the synthesis of thiophenes from 1,4-diaryl-1,3-dienes. Mechanistically, DMSO plays a role of oxidant and S3?- in situ generated from K2S is involved.
Sulfurative self-condensation of ketones and elemental sulfur: A three-component access to thiophenes catalyzed by aniline acid-base conjugate pairs
Nguyen, Thanh Binh,Retailleau, Pascal
supporting information, p. 387 - 390 (2018/02/07)
A sulfurative self-condensation method for constructing thiophenes 2 by a reaction between ketones 1 and elemental sulfur is reported. This reaction, which is catalyzed by anilines and their salts with strong acids, starts from readily available and inexp
Synthesis and properties of Z-1, 3-bis- (aryl)-4-bromo-2-buten-1-ones
Potikha,Turelik,Kovtunenko
experimental part, p. 1184 - 1189 (2010/05/18)
Bromination of 1, 3-bis(aryl)-2-buten-1-ones by N-bromosuccinimide in anhydrous carbon tetrachloride gives Z-1, 3-bis(aryl)-4-bromo-2-buten-1-ones. The effect of the nature of substituent in the benzene ring on the course of a reaction with nucleophiles h
